Effect of zirconia nanoparticles modified by silane coupling agent on some properties of epoxy coating

Dao Phi Hung, Nguyen Thuy Chinh, Nguyen Anh Hiep, Nguyen Xuan Thai, Ly Thi Ngoc Lien, Dao Huu Toan, Hoang Thi Huong Giang, Thai Hoang
Author affiliations

Authors

  • Dao Phi Hung Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nguyen Thuy Chinh Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nguyen Anh Hiep Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nguyen Xuan Thai Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Ly Thi Ngoc Lien Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Dao Huu Toan Chu Van An High School, 10 Thuy Khue, Tay Ho, Ha Noi, Viet Nam
  • Hoang Thi Huong Giang Faculty of Chemistry, Ha Noi National University of Education, 136 Xuan Thuy, Cau Giay, Ha Noi, Viet Nam
  • Thai Hoang Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/16999

Keywords:

epoxy coating, zirconia nanoparticles, modified nanoparticles, anti-corrosion, silane coupling agent

Abstract

Effect of zirconia nanoparticles (zirconia NPs/ZrO2 NPs) modified by 3 wt.% (glycidyloxypropyl) triethoxysilane – GPTES (m-ZrO2 NPs) on some properties of epoxy coating such as mechanical properties, thermal stability and anti-corrosion performance was investigated. The obtained results indicated that the addition of zirconia nanoparticles to epoxy coating could enhance the properties of this coating. The addition of 2 wt.% of pure ZrO2 NPs (u-ZrO2 NPs) to the epoxy matrix could increase the mechanical properties (hardness and adhesion to the steel substrate) by approximately 10 %, the onset temperature of thermal degradation of the epoxy/u-ZrO2 NPs coating was 4.4 oC higher, and the anti-corrosion performance of epoxy coating was improved in comparison with the neat epoxy coating. Organically modified ZrO2 NPs had higher improvement for epoxy coating’s properties than pure ZrO2 NPs. The epoxy coating filled with m-ZrO2 NPs had 19.7 % higher in relative hardness, 88.73 % more in adhesion to steel substrate, 25.6 oC higher in the onset temperature of thermal degradation, and higher anti-corrosion performance in comparison with the epoxy coating filled with 2 wt.% of pure zirconia nanoparticles. The cross-section FESEM images of the epoxy/m-ZrO2 NPs coating showed that m-ZrO2 NPs could regularly disperse in epoxy polymer matrix while unmodified zirconia nanoparticles (u-ZrO2 NPs) were agglomerated to big cluster in the epoxy coating. This was the reason for the high performance of the epoxy coating filled with zirconia NPs modified by GPTES.

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References

Hansson C. M. - The impact of corrosion on society, Metall. Mater. Trans. A 42 A (2011) 2952-2962. DOI: 10.1007/s11661-011-0703-2. DOI: https://doi.org/10.1007/s11661-011-0703-2

Sørensen P. A., Kiil S., Dam-Johansen K., Weinell C. E. - Anticorrosive coatings: a review, J. Coat. Technol. Res. 6 (2) (2009) 135-176. doi:10.1007/s11998-008-9144-2. DOI: https://doi.org/10.1007/s11998-008-9144-2

Verma C., Olasunkanmi L. O., Akpan E. D., Quraishi M. A., Dagdag O., Gouri M. E., Sherif E. S. M., Ebenso E. E. - Epoxy resins as anticorrosive polymeric materials: A review, React. Funct. Polym. 156 (2020) 104741. https://doi.org/10.1016/ j.reactfunctpolym.2020.104741. DOI: https://doi.org/10.1016/j.reactfunctpolym.2020.104741

Jain P., Patidar B., Bhawsar J. - Potential of nanoparticles as a corrosion inhibitor: A Review, J. Bio- Tribo-Corros. 6 (2) (2020). doi:10.1007/s40735-020-00335-0. DOI: https://doi.org/10.1007/s40735-020-00335-0

Anthony C., Kyle J., Christina M., Anne A. and David W. B. - Review: A Review of metal and metal-oxide nanoparticle coating technologies to inhibit agglomeration and increase bioactivity for agricultural applications, Agronomy 10 (2020) 1018. doi:10.3390/agronomy10071018. DOI: https://doi.org/10.3390/agronomy10071018

Wahhab A. J., Abdul M. N. A., Kharia S. H. - Wear response of chopped E-glass fiber reinforced epoxy with various volume fractions and concentration of (ZrO2) nanoparticle, Mater. Today: Proc. 61 (3) (2022) 843-851. https://doi.org/10.1016/j.matpr.2021.09.133. DOI: https://doi.org/10.1016/j.matpr.2021.09.133

Xiaoqian M., Cong P., Dayu Z., Zhanjun W., Shuaidong L., Jingjing W., Nana S. - Synthesis and mechanical properties of the epoxy resin composites filled with sol−gel derived ZrO2 nanoparticles, J. Solgel Sci. Technol. 88 (2018) 442-453. https://doi.org/ 10.1007/s10971-018-4827-3. DOI: https://doi.org/10.1007/s10971-018-4827-3

Dorigato A., Pegoretti A., Bondioli F. and Messori M. - Improving epoxy adhesives with zirconia nanoparticles, Compos. Interfaces 17 (2010) 873-892. DOI:10.1163/092764410X 539253. DOI: https://doi.org/10.1163/092764410X539253

Haddadi S. A., Mahdavian M., Karimi E. - Evaluation of corrosion protection properties of epoxy coating containing sol-gel surface modified nano-zirconia on mild steel, RSC Adv. 5 (2015) 28769-28777. DOI https://doi.org/10.1039/C5RA02127H. DOI: https://doi.org/10.1039/C5RA02127H

Wenhua X., Zhenyu W., En-Hou H., Shuai W. and Qian L. - Corrosion performance of nano-ZrO2 modified coatings in hot mixed acid solutions, Materials 11 (2018) 934. doi:10.3390/ma11060934. DOI: https://doi.org/10.3390/ma11060934

Xinding L., Xitao L., Nan L., Hechuang Z., Yan-Zhen Z., Jiaojiao W., Xia T. - ZrO2 nanoparticle encapsulation of graphene microsheets for enhancing anticorrosion performance of epoxy coatings, Surf. Coat. Technol. 358 (2019) 443-451. https://doi.org/10.1016/j.surfcoat.2018.11.045. DOI: https://doi.org/10.1016/j.surfcoat.2018.11.045

Hung D. P., Chinh N. T., Lan P. T., Dung N. T., Hiep N. A., Lan V. T. N., Trung V. Q., Hieu V. D., Ngan T. T. K., and Hoang T. - Assessment of some characteristics and properties of zirconium dioxide nanoparticles modified with 3-(trimethoxysilyl) propyl methacrylate silane coupling agent, J. Chem. 2021 (2021) Article ID 9925355, 10 pages. doi.org/10.1155/2021/9925355. DOI: https://doi.org/10.1155/2021/9925355

Chinh N. T., Hung D. P., Trung V. Q., Hiep N. A., Thai N. X., Lien L. T. N., Ngan T. T. K., Hoang T. - Assessment of characteristics and weather stability of acrylic coating containing surface modified zirconia nanoparticles, Prog. Org. Coat. 163 (2022) 106675 https://doi.org/10.1016/j.porgcoat.2021.106675. DOI: https://doi.org/10.1016/j.porgcoat.2021.106675

Ruchi A., Smita M. and Sanjay K. N. - High performance epoxy nanocomposite adhesive: Effect of nanofillers on adhesive strength, curing and degradation kinetics, Int. J. Adhes. Adhes. 84 (2018) 238-249. https://doi.org/10.1016/j.ijadhadh.2018.03.013. DOI: https://doi.org/10.1016/j.ijadhadh.2018.03.013

Anh N. T., Hoa N. T., Hang T. T. X., Duong N. T., Truc T. A. - Influence of hydrotalcite containing corrosion inhibitor modified by silane on corrosion protection performance of epoxy coating, VNU J. Sci.: Natural Sci. Technol 33 (2017) 1-7. https://doi.org/10.25073/ 2588-1140/vnunst.4647. DOI: https://doi.org/10.25073/2588-1140/vnunst.4647

Anh N. T., Vuong N. T., Hoang T., Xianming S. - Effect of nanoparticles on the thermal and mechanical properties of epoxy coatings, J. Nanosci. Nanotechnol. 16 (2016) 9874-9881. https://doi.org/10.1166/jnn.2016.12162. DOI: https://doi.org/10.1166/jnn.2016.12162

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Published

31-08-2022

How to Cite

[1]
Dao Phi Hung, “Effect of zirconia nanoparticles modified by silane coupling agent on some properties of epoxy coating”, Vietnam J. Sci. Technol., vol. 60, no. 4, pp. 664–674, Aug. 2022.

Issue

Vol. 60 No. 4 (2022)

Section

Materials

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