Characteristics, properties and morphology of calcium silicate nanoparticles modified with some silane coupling agents

Nguyen Anh Hiep; Nguyen Thuy Chinh; Mai Duc Huynh; Dao Phi Hung; Phung Thi Lan; Nguyen Tien Dung; Nguyen Thi Nga; Thai Hoang

doi:10.15625/2525-2518/16557

Author affiliations

Authors

Nguyen Anh Hiep Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Street, Cau Giay District, Ha Noi, Viet Nam
Nguyen Thuy Chinh Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Street, Cau Giay District, Ha Noi, Viet Nam
Mai Duc Huynh Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Street, Cau Giay District, Ha Noi, Viet Nam
Dao Phi Hung Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Street, Cau Giay District, Ha Noi, Viet Nam
Phung Thi Lan Faculty of Chemistry, Hanoi National University of Education, No. 36 Xuan Thuy Street, Cau Giay District, Ha Noi, Viet Nam
Nguyen Tien Dung Faculty of Chemistry, Hanoi National University of Education, No. 36 Xuan Thuy Street, Cau Giay District, Ha Noi, Viet Nam
Nguyen Thi Nga Hanoi Medical College, 35 Doan Thi Diem Street, Dong Da District, Ha Noi, Viet Nam
Thai Hoang Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet Street, Cau Giay District, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/16557

Keywords:

calcium silicate, surface modification, silane coupling agent, grafting yield, hydrolysis method

Abstract

This paper presents the characteristics, properties and morphology of calcium silicate (CS) nanoparticles modified with silane coupling agents, namely vinyltrimetoxy silane (VTMS) and 3-(trimethoxysilyl)propyl methacrylate silane (MPTS), by the hydrolysis method. Effect of content of silane coupling agents on CS nanoparticles modified was investigated. The obtained results suggested that silane coupling agents were successfully grafted onto the surface of CS nanoparticles. The performance and amount of silane coupling agent grafting on CS nanoparticles depended on the nature and initial content of silane coupling agent. The highest grafting yield on CS nanoparticles performances was 32.8 % for VTMS at initial content of 5 wt. % and 48.80% for MPTS at initial content of 10 wt. %. Organo-modification decreased thermo-oxidation stability of modified CS nanoparticles because of the decomposition of organic moiety in silane coupling agent while hydrophobicity of modified CS surface increased. Thus, agglomeration of modified CS nanoparticles reduced significantly. The unmodified CS nanoparticles had size distribution (in distilled water) peak at nearly 500 nm while the size distribution (in distilled water) peak of CS modified 10 wt.% MPTS was approximately 150nm.

Downloads

Download data is not yet available.

References

Rangavar H., Khosro S. K., Javy M. T. - The effect of nano wollastonite on the fire resistance and the adhesion properties of water based acrylic coating on wood surface, Iranian journal of Wood and Paper Science Research 33 (2) (2018) 178.

Tiimob B. J., Rangari V. K., Jeelani S. - Effect of reinforcement of sustainable b-CaSiO3 nanoparticles in bio-based epoxy resin system, Journal of Applied Polymer Science 131 (2014) 40867. DOI: https://doi.org/10.1002/app.40867

Sinkovec R., Music B. - Effect of organosilane coupling agents on thermal, rheological and mechanical properties of silicate-filled epoxy molding compound, Materials (Basel) 13 (1) (2020) 177. DOI: https://doi.org/10.3390/ma13010177

Chen Q., Xiu-Yin Z., Bang-Shang Z., Kai-Li L., Jiang C., Xin-Jing Z. - The effect of CaSiO3 nano-particles reinforced denture polymethyl methacrylate, Advanced Composites Letters 20 (1) (2011) 5-12. DOI: https://doi.org/10.1177/096369351102000102

Yu-rong Y., Qing-jie Z., Wei C., Mei-gui Y., LanX. - Formation and application of hierarchical calcium silicate-calcium sulfate whiskers, Materials & Design 146 (2018) 172-179. DOI: https://doi.org/10.1016/j.matdes.2018.03.018

Minet J., Abramson S., Bresson B., Sanchez C., Montouillot V., Lequeux N. - Newlayered calcium organosilicate hybrids with covalently linked organic functionalities, Chemistry of Materials 16 (2004) 3955-3962. DOI: https://doi.org/10.1021/cm034967o

Minet J., Abramson S., Bresson B., Franceschini A., Van Damme H., Lequeux N. -Organic calcium silicate hydrate hybrids : a new approach to cement based nanocomposites, Journal of Materials Chemistry 16 (2006) 1379-1383. DOI: https://doi.org/10.1039/b515947d

Franceschini A., Abramson S., Mancini V., Bresson B., Chassenieux C., Lequeux N. -New covalent bonded polymer–calcium silicate hydrate composites, Journal of Materials Chemistry 17 (2007) 913-922. DOI: https://doi.org/10.1039/B613077A

Zheyu Z., Zhongping W., Yue Z., Yongqi W., Anming S. - Synthesis and structure of calcium silicate hydrate (C-S-H) modified by hydroxyl-terminated polydimethylsiloxane (PDMS), Construction and Building Materials 267 (2021) 18. DOI: https://doi.org/10.1016/j.conbuildmat.2020.120731

Ohtsuki C., Miyazaki T., Kamitakahara M., Tanihara M. - Design of novel bioactive materials through organic modification of calcium silicate, Journal of the European Ceramic Society 27 (2007) 1527-1533. DOI: https://doi.org/10.1016/j.jeurceramsoc.2006.04.018

Liu Q., Ding J., Chambers D.E., Debnath S., Wunder S. L., Baran G.R. - Filler-coupling agentmatrix interactions in silica/polymethylmethacrylate composites, Journal of Biomedical Materials Research 57 (3) (2001) 384-93. DOI: https://doi.org/10.1002/1097-4636(20011205)57:3<384::AID-JBM1181>3.0.CO;2-F

Posthumus W., Magusin P. C. M. M., Brokken-Zijp J. C. M., Tinnemans A. H. A., Van der Linde R. - Surface modification of oxidic nanoparticles using 3-methacryloxypropy-ltrimethoxysilane, Journal of Colloid and Interface Science 269 (1) (2004) 109-125. DOI: https://doi.org/10.1016/j.jcis.2003.07.008

Yu P., Kirkpatrick R. J., Poe B., McMillan P. F., Cong X. - Structure of calcium silicate hydrate (C-S-H): Near-, Mid-, and Far-Infrared spectroscopy, Journal of the American Ceramic Society 82 (3) (2004) 742-748. DOI: https://doi.org/10.1111/j.1151-2916.1999.tb01826.x

Lopes I. M. F., Abersfelder K., Oliveira P. W., Mousavi S. H., Junqueira R. M. R. - Flower-like silicon dioxide/polymer composite particles synthesized by dispersion polymerization route, Journal of Materials Science 53 (2018) 11367-11377 DOI: https://doi.org/10.1007/s10853-018-2378-1

Lin-Vien D., Colthup N. B., Fateley W. G., Grasselli J. G. - The Handbook of infrared and raman characteristic frequencies of organic molecules, Elsevier Inc., 1991 (ISBN 978-0-12-451160-6).

Reddy M. V., Pathak M. - In vitrobiological evaluations of Zn doped CaSiO3 synthesized by sol–gel combustion technique -Journal of Inorganic and Organometallic Polymers and Materials 28 (2018) 2187-2195. DOI: https://doi.org/10.1007/s10904-018-0922-8

Zhang Z., Shao H., Lin T., Zhang Y., He J., Wang L. - 3D gel printing of porous calcium silicate scaffold for bone tissue engineering, Journal of Materials Science 54 (2019) 10430-10436. DOI: https://doi.org/10.1007/s10853-019-03626-1

Peng L., Qisui W., Xi L., Chaocan Z. - Investigation of the states of water and OH groups on the surface of silica, Colloids and Surfaces A: Physicochemical and Engineering Aspects 334 (2009) 112-115. DOI: https://doi.org/10.1016/j.colsurfa.2008.10.028

Zhijian W., Xiang H., Taehoon K., Myung-Suk C., Kangtaek L. - Surface properties of submicrometer silica spheres modiﬁed withaminopropyltriethoxysilane and phenyltriethoxysilane, Journal of Colloid and Interface Science 304 (2004) 119-124. DOI: https://doi.org/10.1016/j.jcis.2006.08.055

Hui P., Xiao Dong W., Sha Sha X., Lai Gui Y., Zhi Jun Z. - Preparation and characterization of TiO2 nanoparticles surface-modified by octadecyltrimethoxysilane, Indian Journal of Engineering and Materials Sciences 20 (2013) 561-567.