Assessing the corrosion protection of 8-hydroxyquinoline-cerium (III) complex for carbon steel in a NaCl solution

Anh Son Nguyen, Thuy Duong Nguyen, To Thi Xuan Hang, Thi Vy Anh Vuong, Thu Thuy Pham, Thu Thuy Thai, Anh Truc Trinh, Nadine Pébère
Author affiliations

Authors

  • Anh Son Nguyen Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam https://orcid.org/0000-0002-7221-3369
  • Thuy Duong Nguyen Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • To Thi Xuan Hang Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Thi Vy Anh Vuong Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Thu Thuy Pham Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Thu Thuy Thai Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam https://orcid.org/0000-0002-0901-2388
  • Anh Truc Trinh Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nadine Pébère 3Université de Toulouse, CIRIMAT, UPS/INPT/CNRS, ENSIACET, 4, allée Emile Monso BP 44362, Toulouse 31432 Cedex 4, France https://orcid.org/0000-0002-2728-0917

DOI:

https://doi.org/10.15625/2525-2518/19391

Keywords:

8-Hydroxyquinoline Complex, corrosion inhibitor, electrochemical impedance spectroscopy, cerium (III) ions

Abstract

In the present study, a complex between 8-hydroxyquinoline and cerium (III) (Ce-HQ) was synthesized in the presence of triethylamine. Afterwards, the complex was characterized by Field Emission Scanning Electron Microscopy (FESEM), Fourier-transform infrared spectroscopy (FTIR) and Thermo-Gravimetric Analysis (TGA). The inhibition efficiency of the Ce-HQ complex for the corrosion of carbon steel, evaluated by both Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic Polarization (PP) plots, reached 90 % after 2 h of immersion in a 0.01 M NaCl solution. Then, EIS measurements were carried out to evaluate the effect of the Ce-HQ complex, as inhibitive pigment, after incorporation in a waterborne epoxy coating applied over carbon steel plate. The total resistance (Rtotal) of the coated sample containing the Ce-HQ complex was higher (3.6 x 107 Ω cm2), after 35 days of exposure in a 0.5 M NaCl solution than the values obtained for the coating without Ce-HQ. The results showed that the EP/Ce-HQ coating provided not only corrosion protection by the Ce (III) ions and 8HQ release at the metal/coating interface, but also improved the barrier properties. This work proposed a new type of inhibitive pigments which can be used to develop effective coatings for corrosion protection.

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Published

23-02-2024

How to Cite

[1]
A. S. Nguyen, “Assessing the corrosion protection of 8-hydroxyquinoline-cerium (III) complex for carbon steel in a NaCl solution”, Vietnam J. Sci. Technol., vol. 62, no. 2, pp. 299–311, Feb. 2024.

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Materials