Green synthesis of nanostructured 1T/2H-MoS2 hybrid phase with polyol solvents and microwave heating
Author affiliations
DOI:
https://doi.org/10.15625/2525-2518/18507Keywords:
nano MoS2, hybrid phase 1T/2H-MoS2, polyol solvents, microwave synthesis, green chemistryAbstract
Green synthesis approaches have attracted greatly of attention in recent years since they address the issues associated with sustainability than conventional synthesis methods. New research fields in green nanoscience are being developed as a result of the incorporation of green chemistry principles into nanoscience. In this paper, the successful microwave-assisted green synthesis of MoS2 nanoparticles in a single pot using polyol solvents such as ethylene glycol and glycerol is demonstrated. The coexistence of 1T and 2H phases in MoS2 nanomaterials was determined using advanced techniques such as XRD, Raman, XPS, and TEM images. The highest 1T proportion obtained was 84.5% when compared to the 2H phase. The reaction mechanism and the phase transition between 1T and 2H were described and illustrated. The role of polyol solvents in the practical synthesis of nano MoS2 under microwave heating is also evaluated and explained. Due to the ability of the metallic 1T phase to enhance electrical conductivity, it is believed that hybrid nanostructures exhibit superior electrochemical performance for energy storage and conversion applications.
Downloads
References
Wang D., Zhang X., Bao S., Zhang Z., Fei H., and Wu Z. - Phase engineering of a multiphasic 1T/2H MoS2 catalyst for highly efficient hydrogen evolution, J. Mater. Chem. A, 9 (6) (2017) 2681-2688. https://doi.org/10.1039/C6TA09409K DOI: https://doi.org/10.1039/C6TA09409K
Tang Q. and Jiang D.-e. - Mechanism of Hydrogen Evolution Reaction on 1T-MoS2 from First Principles, ACS Catal., 6 (8) (2016) 4953-4961. https://doi.org/10.1021/acscatal.6b01211
Damien Voiry M. S., Silva R., Fujita T., Chen M., Asefa T., Shenoy Vivek B., Eda G., and Chhowalla M. - Conducting MoS2 nanosheets as catalysts for hydrogen evolution reaction, Nano Lett., 13 (12) (2013) 6222-6227. https://doi.org/10.1021/nl403661s DOI: https://doi.org/10.1021/nl403661s
Yang J., Wang K., Zhu J., Zhang C., and Liu T. - Self-Templated Growth of Vertically Aligned 2H-1T MoS2 for Efficient Electrocatalytic Hydrogen Evolution, ACS Appl. Mater. Interfaces., 8 (46) (2016) 31702-31708. https://doi.org/10.1021/acsami.6b11298 DOI: https://doi.org/10.1021/acsami.6b11298
Zhou Y. et al. - Rational design and synthesis of 3D MoS2 hierarchitecture with tunable nanosheets and 2H/1T phase within graphene for superior lithium storage, Electrochim. Acta., 211 (2016) 1048-1055. https://doi.org/10.1016/j.electacta.2016.06.123 DOI: https://doi.org/10.1016/j.electacta.2016.06.123
Wu M. et al. - Metallic 1T MoS2 nanosheet arrays vertically grown on activated carbon fiber cloth for enhanced Li-ion storage performance, J. Mater. Chem. A, 5 (27) (2017) 14061-14069. https://doi.org/10.1039/C7TA03497K DOI: https://doi.org/10.1039/C7TA03497K
Wang D., Xiao Y., Luo X., Z. Wu, Wang Y.-J., and Fang B. - Swollen Ammoniated MoS2 with 1T/2H Hybrid Phases for High-Rate Electrochemical Energy Storage, ACS Sustain Chem Eng., 5 (3) (2017) 2509-2515. https://doi.org/10.1021/acssuschemeng.6b02863 DOI: https://doi.org/10.1021/acssuschemeng.6b02863
Jiang L. et al. - Optimizing Hybridization of 1T and 2H Phases in MoS2 Monolayers to Improve Capacitances of Supercapacitors, Mater. Res. Lett., 3 (4) (2015) 177-183. https://doi.org/10.1080/21663831.2015.1057654 DOI: https://doi.org/10.1080/21663831.2015.1057654
Huang H. et al. - Metallic 1T phase MoS2 nanosheets for high-performance thermoelectric energy harvesting, Nano Energy, 26 (2016) 172-179. https://doi.org/10.1016/j.nanoen.2016.05.022 DOI: https://doi.org/10.1016/j.nanoen.2016.05.022
Hsiao M.-C. et al. - Ultrathin 1T-phase MoS2 nanosheets decorated hollow carbon microspheres as highly efficient catalysts for solar energy harvesting and storage, J. Power Sources, 345 (2017) 156-164. https://doi.org/10.1016/j.jpowsour.2017.01.132 DOI: https://doi.org/10.1016/j.jpowsour.2017.01.132
Gigot A. et al. - Mixed 1T–2H Phase MoS2/Reduced Graphene Oxide as Active Electrode for Enhanced Supercapacitive Performance, ACS Appl. Mater. Interfaces., 8 (48) (2016) 32842-32852. https://doi.org/10.1021/acsami.6b11290 DOI: https://doi.org/10.1021/acsami.6b11290
Tang Q. and Jiang D.-e. - Mechanism of Hydrogen Evolution Reaction on 1T-MoS2 from First Principles, ACS Catal., 6 (8) (2016) 4953-4961. https://doi.org/10.1021/acscatal.6b01211 DOI: https://doi.org/10.1021/acscatal.6b01211
Zhang Y., Kuwahara Y., Mori K., Louis C., and Yamashita H., - Hybrid phase 1T/2H-MoS2 with controllable 1T concentration and its promoted hydrogen evolution reaction, Nanoscale, 12 (22) (2020) 11908-11915. https://doi.org/10.1039/D0NR02525A DOI: https://doi.org/10.1039/D0NR02525A
Geng X. et al. - Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction, Nat. Commun., 7 (1) (2016) 10672. https://doi.org/10.1038/ncomms10672 DOI: https://doi.org/10.1038/ncomms10672
Lei Z., Zhan J., Tang L., Zhang Y., and Wang Y. - Recent Development of Metallic (1T) Phase of Molybdenum Disulfide for Energy Conversion and Storage, Adv. Energy Mater. 8 (19) 1703482 (2018). https://doi.org/10.1002/aenm.201703482 DOI: https://doi.org/10.1002/aenm.201703482
Liu Q. et al. - Gram-Scale Aqueous Synthesis of Stable Few-Layered 1T-MoS2: Applications for Visible-Light-Driven Photocatalytic Hydrogen Evolution, Small,11 (41) (2015) 5556-5564. https://doi.org/10.1002/smll.201501822 DOI: https://doi.org/10.1002/smll.201501822
Chen Y.-X., Wu C.-W., Kuo T.-Y., Chang Y.-L., Jen M.-H., and Chen I. W. P. - Large-Scale Production of Large-Size Atomically Thin Semiconducting Molybdenum Dichalcogenide Sheets in Water and Its Application for Supercapacitor, Sci. Rep., 6 (1) (2016) 26660. https://doi.org/10.1038/srep26660 DOI: https://doi.org/10.1038/srep26660
Ali M. E. M., Mohammed R., Abdel-Moniem S. M., El-Liethy M. A., and Ibrahim H. S. - Green MoS2 nanosheets as a promising material for decontamination of hexavalent chromium, pharmaceuticals, and microbial pathogen disinfection: spectroscopic study, J Nanopart Res., 24 (10) (2022). https://doi.org/10.1007/s11051-022-05573-6 DOI: https://doi.org/10.1007/s11051-022-05573-6
Pallikkarathodi Mani N. and Cyriac J. - Green approach to synthesize various MoS2 nanoparticles via hydrothermal process, Bull. Mater. Sci., 45 (4) (2022). https://doi.org/10.1007/s12034-022-02757-7 DOI: https://doi.org/10.1007/s12034-022-02757-7
Madani M. et al. - Green synthesis of nanoparticles for varied applications: Green renewable resources and energy-efficient synthetic routes, Nanotechnol. Rev., 11 (1) (2022) 731-759. https://doi.org/10.1515/ntrev-2022-0034 DOI: https://doi.org/10.1515/ntrev-2022-0034
Priecel P. and Lopez-Sanchez J. A. - Advantages and Limitations of Microwave Reactors: From Chemical Synthesis to the Catalytic Valorization of Biobased Chemicals, ACS Sustain Chem Eng, 7 (1) (2019) 3-21. https://doi.org/10.1021/acssuschemeng.8b03286 DOI: https://doi.org/10.1021/acssuschemeng.8b03286
Dong H., Chen Y. C., and Feldmann C. - Polyol synthesis of nanoparticles: status and options regarding metals, oxides, chalcogenides, and non-metal elements, Curr. Green Chem., 17 (8) (2015) 4107-4132. https://doi.org/10.1039/C5GC00943J DOI: https://doi.org/10.1039/C5GC00943J
Collins T. J. - Review of the twenty-three year evolution of the first university course in green chemistry: teaching future leaders how to create sustainable societies, J. Clean. Prod., 140 (2017) 93-110. https://doi.org/10.1016/j.jclepro.2015.06.136 DOI: https://doi.org/10.1016/j.jclepro.2015.06.136
Castillo-Henriquez L., Alfaro-Aguilar K., Ugalde-Alvarez J., Vega-Fernandez L., Montes de Oca-Vasquez G., and Vega-Baudrit J. R. - Green Synthesis of Gold and Silver Nanoparticles from Plant Extracts and Their Possible Applications as Antimicrobial Agents in the Agricultural Area, Nanomaterials (Basel), 10 (9) (2020). https://doi.org/10.3390/nano10091763 DOI: https://doi.org/10.3390/nano10091763
Waskito I. S., Kurniawan B., Amal M. I., and Hanifuddin M. - The Effect of Precursors Concentration on the Structural Properties of MoS2 Nanosheet-Microsphere Synthesized Via Hydrothermal Route, IOP Conf. Ser. Mater. Sci. Eng., 546 (2019). http://dx.doi.org/10.1088/1757-899X/546/4/042048 DOI: https://doi.org/10.1088/1757-899X/546/4/042048
Wang F., Li G., Zheng J., Ma J., Yang C., and Wang Q. - Hydrothermal synthesis of flower-like molybdenum disulfide microspheres and their application in electrochemical supercapacitors, RSC Adv., 8 (68) 92018) 38945-38954. https://doi.org/10.1039/C8RA04350G DOI: https://doi.org/10.1039/C8RA04350G
Suo Xia Hou C. W., Jie Huo Y. - Controllable Preparation of Nano Molybdenum Disulfide by Hydrothermal Method, Ceram. - Silik., 61 (2) (2017) 158 - 162, 2017. https://doi.org/10.13168/cs.2017.0011 DOI: https://doi.org/10.13168/cs.2017.0011
Saber M., Khabiri G., Khabiri A. M., Ulbricht M., Khalil A., and M. R - A comparative study on the photocatalytic degradation of organic dyes using hybridized 1T/2H, 1T/3R and 2H MoS2 nano-sheets, RSC Adv., 8 (2018) 26364-26370. https://doi.org/10.1039/C8RA05387A DOI: https://doi.org/10.1039/C8RA05387A
Saseendran S. B., Ashok A., and A. A S - Edge terminated and interlayer expanded pristine MoS2 nanostructures with 1T on 2H phase, for enhanced hydrogen evolution reaction, Int. J. Hydrogen Energy., 47 (16) (2022) 9579-9592. https://doi.org/10.1016/j.ijhydene.2022.01.031 DOI: https://doi.org/10.1016/j.ijhydene.2022.01.031
Das S., Swain G., and Parida K. - One step towards the 1T/2H-MoS2 mixed phase: a journey from synthesis to application, Mater. Chem. Front., 5 (5) (2021) 2143-2172. https://doi.org/10.1039/D0QM00802H
Das S., Swain G., and Parida K. - One step towards the 1T/2H-MoS2 mixed phase: a journey from synthesis to application, Mater. Chem. Front., 5 (5) (2021) 2143-2172. https://doi.org/10.1039/D0QM00802H DOI: https://doi.org/10.1039/D0QM00802H
Wang H. W., Skeldon P., and Thompson G. E. - XPS studies of MoS2 formation from ammonium tetrathiomolybdate solutions, Surf. Coat. Int., 91 (3) (1997) 200-207. https://doi.org/10.1016/S0257-8972(96)03186-6 DOI: https://doi.org/10.1016/S0257-8972(96)03186-6
John F. Moulde W. F. S., Peter E. S., Kenneth Bomben D. - Handbook of X-ray photoelectron spectroscopy, 1992
Cheng P., Sun K., and Hu Y. H. - Memristive Behavior and Ideal Memristor of 1T Phase MoS2 Nanosheets, Nano Lett., 16 (1) (2016) 572-576. https://doi.org/10.1021/acs.nanolett.5b04260 DOI: https://doi.org/10.1021/acs.nanolett.5b04260
Hou M. et al. - Aging mechanism of MoS2 nanosheets confined in N-doped mesoporous carbon spheres for sodium-ion batteries, Nano Energy, 62 (2019) 299-309. https://doi.org/10.1016/j.nanoen.2019.05.048 DOI: https://doi.org/10.1016/j.nanoen.2019.05.048
Gao X., Xiong L., Wu J., Wan J., and Huang L. - Scalable and controllable synthesis of 2D high-proportion 1T-phase MoS2, Nano Research, 13 (11) (2020) 2933-2938. https://doi.org/10.1007/s12274-020-2950-2 DOI: https://doi.org/10.1007/s12274-020-2950-2
Xin X. et al. - In-situ growth of high-content 1T phase MoS2 confined in the CuS nanoframe for efficient photocatalytic hydrogen evolution, Appl. Catal. B: Enviro., 269 (2020) 118773. https://doi.org/10.1016/j.apcatb.2020.118773 DOI: https://doi.org/10.1016/j.apcatb.2020.118773
Feng D., Pan X., Xia Q., Qin J., Zhang Y., and Chen X. - Metallic MoS2 nanosphere electrode for aqueous symmetric supercapacitors with high energy and power densities, J. Mater. Sci., 55 (2020) 1-11. https://doi.org/10.1007/s10853-019-03997-5 DOI: https://doi.org/10.1007/s10853-019-03997-5
Yu Y. et al. - High phase purity 1T'-MoS2 and 1T'-MoSe2 layered crystals - Nat Chem, 10 (6) (2018) 638-643. https://doi.org/10.1038/s41557-018-0035-6 DOI: https://doi.org/10.1038/s41557-018-0035-6
Wei J. et al. - Synthesis of Few Layer Amorphous 1T/2H MoS2 by a One-Step Ethanol/Water Solvothermal Method and Its Hydrodesulfurization Performance, Catal. Letters, 152 (1) (2021) 263-275. https://doi.org/10.1007/s10562-021-03621-9 DOI: https://doi.org/10.1007/s10562-021-03621-9
Wang S., Luo Y., Fan Y., Ali A., Liu Z., and Kang Shen P. - Uniformly distributed 1T/2H-MoS2 nanosheets integrated by melamine foam-templated 3D graphene aerogels as efficient polysulfides trappers and catalysts in lithium-sulfur batteries, J. Electroanal.Chem., 909 (2022). https://doi.org/10.1016/j.jelechem.2022.116099 DOI: https://doi.org/10.1016/j.jelechem.2022.116099
Agrawal A. V. et al. - Controlled Growth of MoS2 Flakes from in-Plane to Edge-Enriched 3D Network and Their Surface-Energy Studies, ACS Appl. Nano Mater. 1 (5) (2018) 2356-2367. https://doi.org/10.1021/acsanm.8b00467 DOI: https://doi.org/10.1021/acsanm.8b00467
Kim J. S. et al. - Electrical Transport Properties of Polymorphic MoS2, ACS Nano, 10 (8) (2016 7500-7506. https://doi.org/10.1021/acsnano.6b02267 DOI: https://doi.org/10.1021/acsnano.6b02267
Lee Y. B. et al. - Facile microwave assisted synthesis of vastly edge exposed 1T/2H-MoS2 with enhanced activity for hydrogen evolution catalysis, J. Mater. Chem., 7 (8) (2013) 3563-3569. https://doi.org/10.1039/C8TA12080C DOI: https://doi.org/10.1039/C8TA12080C
Cai L. et al. - High-Content Metallic 1T Phase in MoS2-Based Electrocatalyst for Efficient Hydrogen Evolution, J. Phys. Chem. C, 121 (28) (2017) 15071-15077,. https://doi.org/10.1021/acs.jpcc.7b03103 DOI: https://doi.org/10.1021/acs.jpcc.7b03103
Guo X., Wang Z., Zhu W., and Yang H. - The novel and facile preparation of multilayer MoS2 crystals by a chelation-assisted sol–gel method and their electrochemical performance, RSC Adv., 7 (15) (2017) 9009-901. https://doi.org/10.1039/C6RA25558B DOI: https://doi.org/10.1039/C6RA25558B
Wojnarowicz J. et al. - Effect of Water Content in Ethylene Glycol Solvent on the Size of ZnO Nanoparticles Prepared Using Microwave Solvothermal Synthesis, J. Nanomater., 2016 (2016) 1-15. https://doi.org/10.1155/2016/2789871 DOI: https://doi.org/10.1155/2016/2789871
Zheng Y. et al. - The effect of lithium adsorption on the formation of 1T-MoS2 phase based on first-principles calculation, Phys. Lett. A, 380 (20) (2016) 1767-1771. https://doi.org/10.1016/j.physleta.2016.03.009 DOI: https://doi.org/10.1016/j.physleta.2016.03.009
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Vietnam Journal of Sciences and Technology (VJST) is an open access and peer-reviewed journal. All academic publications could be made free to read and downloaded for everyone. In addition, articles are published under term of the Creative Commons Attribution-ShareAlike 4.0 International (CC BY-SA) Licence which permits use, distribution and reproduction in any medium, provided the original work is properly cited & ShareAlike terms followed.
Copyright on any research article published in VJST is retained by the respective author(s), without restrictions. Authors grant VAST Journals System a license to publish the article and identify itself as the original publisher. Upon author(s) by giving permission to VJST either via VJST journal portal or other channel to publish their research work in VJST agrees to all the terms and conditions of https://creativecommons.org/licenses/by-sa/4.0/ License and terms & condition set by VJST.
Authors have the responsibility of to secure all necessary copyright permissions for the use of 3rd-party materials in their manuscript.
Vietnam Journal of Science and Technology (VJST) is pleased to notice: