Fabrication of flexible multilayer transparent electrode based on silver nanowire, graphene oxide, and poly(3,4-ethylenedioxythiophene): polystyrene sulfonate

Thi Thu Hien Nguyen, Minh Hoang Nguyen, Minh Triet Khong, Thi Kim Dung Nguyen, Tien Dat Doan, Nhung Hac Thi, Ho Thi Oanh, Nguyen Duc Tuyen, Dinh Long Phan, Tuyen Van Nguyen, Mai Ha Hoang
Author affiliations

Authors

  • Thi Thu Hien Nguyen Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Minh Hoang Nguyen Viet Yen 1 High School, Viet Yen, Bac Giang, Viet Nam
  • Minh Triet Khong Viet Yen 1 High School, Viet Yen, Bac Giang, Viet Nam
  • Thi Kim Dung Nguyen Viet Yen 1 High School, Viet Yen, Bac Giang, Viet Nam
  • Tien Dat Doan Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nhung Hac Thi Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Ho Thi Oanh Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nguyen Duc Tuyen Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Dinh Long Phan College of Economics - Technology of Industry and Commerce, 569 Quang Trung, Thanh Hoa City, Thanh Hoa, Viet Nam
  • Tuyen Van Nguyen Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Mai Ha Hoang Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/16661

Keywords:

Flexible transparent electrode, silver nanowire, graphene oxide, PEDOT:PSS

Abstract

High-performance flexible multilayer transparent conducting electrodes (TCE) based on silver nanowires (AgNWs), graphene oxide (GO), and poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) materials on the flexible polyethylene terephthalate (PET) substrate were successfully fabricated by spin-coating technique. The multilayer electrodes were fabricated using different combinations of AgNWs, GO, and PEDOT:PSS materials. The morphological, physical properties, surface roughness, and durability of the fabricated electrodes were investigated. The results indicated that the five-layer structured electrode of PEDOT:PSS/GO/AgNW/GO/PEDOT:PSS possesses the best performance with a sheet resistance of 23 Ω/sq, transmittance of 85 %, and the figure of merit (FoM) value of 8.6, which is equivalent to the commercial ITO electrode. Besides, the five-layer structured electrode possessed a surface roughness of only 8 nm. The PEDOT:PSS/GO/AgNW/GO/PEDOT:PSS electrode also exhibited high durability after being exposed to the environment for 30 days. Owing to the combination of AgNWs, GO, and PEDOT: PSS materials, the five-layer electrode of PEDOT:PSS/GO/AgNW/GO/PEDOT:PSS improved the inherent disadvantages of AgNWs electrodes. In addition, the electrode possessed good conductivity, high stability, low cost, and simplicity. The electrode can be used as a promising electrode in optoelectronic devices.

Downloads

Download data is not yet available.

References

Jinhong D., Songfeng P., Laipeng M., Hui M. C. - 25th anniversary article: Carbon nanotube- and graphene-based transparent conductive films for optoelectronic devices, Adv. Mater 26 (2014) 1958-1991. https://doi.org/10.1002/adma.201304135. DOI: https://doi.org/10.1002/adma.201304135

Shengrong Y., Aaron R. R., Zuofeng C., Ian E. S., Benjamin J. W. - Metal nanowire networks: The next generation of transparent conductors, Adv. Mater 26 (2014) 6670-6687. https://doi.org/10.1002/adma.201402710. DOI: https://doi.org/10.1002/adma.201402710

Seok I. N., Seok S. K., Jang J., Dong Y. K. - Efficient and flexible ITO-free organic solar cells using highly conductive polymer anodes, Adv. Mater 20 (2008) 4061–4067. https://doi.org/10.1002/adma.200800338. DOI: https://doi.org/10.1002/adma.200800338

Churl S. L., Joung E. Y., Kwonwoo S., Park C. O., Joonho B. - Carbon nanotube-silver nanowire composite networks on flexible substrates: high reliability and application for supercapacitor electrodes, Phys. Status Solidi A 211 (2014) 2890-2897. https://doi.org/10.1002/pssa.201431538. DOI: https://doi.org/10.1002/pssa.201431538

Zongyou Y., Shuangyong S., Teddy S., Shixin W., Xiao H., Qiyuan H., Yeng M. L., Hua Z. - Organic photovoltaic devices using highly flexible reduced graphene oxide films as transparent electrodes, ACS Nano 4 (2010) 5263-5268. https://doi.org/10.1021/nn1015874. DOI: https://doi.org/10.1021/nn1015874

Youn S. K., Eun J. L., Jun T. L., Do K. H., Won K. C., Jin Y. K. - High-performance flexible transparent electrodes films based on silver nanowire-PEDOT:PSS hybrid-gels, RSC Adv 6 (2016) 64428-64433. https://doi.org/10.1039/C6RA06590B. DOI: https://doi.org/10.1039/C6RA06590B

Zhuang C. W., Zhihong. C., Xu D., Jonathan M. L., Jennifer S., Maria N., Katalin K., John R. R., David B. T., Arthur F. H., Andrew G. R. - Transparent, conductive carbon nanotube films, Science 305 (2004) 1273-1276. https://doi.org/10.1126/science.1101243. DOI: https://doi.org/10.1126/science.1101243

Chunxiong B., Jie Y., Hao G., Faming L., Yingfang Y., Bo Y., Gao F., Xiaoxin Z., Tao Y., Yiqiang Q., Jianguo L., Zhigang Z. - In situ fabrication of highly conductive metal nanowire networks with high transmittance from deep-ultraviolet to near-infrared, ACS Nano 9 (2015) 2502-2509. https://doi.org/10.1021/nn504932e. DOI: https://doi.org/10.1021/nn504932e

Daniel L., Gael G., Celine M., Caroline C., Daniel B., Jean P. S. - Flexible transparent conductive materials based on silver nanowire networks: a review, Nanotechnology 24 (2013) 452001. https://doi.org/10.1088/0957-4484/24/45/452001. DOI: https://doi.org/10.1088/0957-4484/24/45/452001

Yasin A., Mahmut T., İsmail B., Ali D., Ayse B. - Solution-processed transparent conducting electrodes with graphene, silver nanowires and PEDOT:PSS as alternative to ITO, Surface & Coatings Technology 302 (2016) 75-81. https://doi.org/10.1016/j.surfcoat.2016.05.058. DOI: https://doi.org/10.1016/j.surfcoat.2016.05.058

Pham T. T., Le V. T., Tran V. K., Tran X. D., Chau N. T. N., Tran T. T. N., Le M. T., Nguyen N. V., Nguyen M. H. - Synthesis of Ag/GO nanocomposite with promising photocatalytic ability for reduction reaction of p-nitrophenol, Mater. Res. Express 8 (2021) 105009. https://doi.org/10.1088/2053-1591/ac2ead. DOI: https://doi.org/10.1088/2053-1591/ac2ead

Jiajie L., Lu L., Kwing T., Zhi R., Wei H., Xiaofan N., Yongsheng C., Qibing P. - Silver nanowire percolation network soldered with graphene oxide at room temperature and its application for fully stretchable polymer light-emitting diodes, ACS nano 8 (2014) 1590–1600. https://doi.org/10.1021/nn405887k. DOI: https://doi.org/10.1021/nn405887k

Jinhwan L., Phillip L., Ha B. L., Sukjoon H., Inhwa L., Junyeob Y., Seung S. L., Taek S. K., Dongjin L., Seung H. K. - Room-temperature nanosoldering of a very long metal nanowire network by conducting-polymer-assisted joining for a flexible touchpanel application, Adv. Funct. Mater 23 (2013) 4171-4176. https://doi.org/10.1002/adfm.201203802. DOI: https://doi.org/10.1002/adfm.201203802

Young U. K., Su H. P., Nguyen T. N., Mai H. H., Min J. C., Dong H. C. - Optimal Design of PEDOT:PSS Polymer-Based Silver Nanowire Electrodes for realization of Flexible Polymer Solar Cells, Macromolecular Research 29 (2021) 75-81. https://doi.org/10.1007/s13233-021-9005-8. DOI: https://doi.org/10.1007/s13233-021-9005-8

Nguyen T. N., Pham D. L., Doan T. D., Min J. C., Dong H. C., Hoang M. H. - Optimization of silver nanowire synthesis for flexible transparent conductive electrodes, Vietnam J. Chem 59 (1) (2021) 98-105. https://doi.org/10.1002/vjch.202000131.

Ayrat M. D., James M. T. - Mechanism of graphene oxide formation, ACS Nano 8(3) (2014) 3060-3068. https://doi.org/10.1021/nn500606a. DOI: https://doi.org/10.1021/nn500606a

Syang-Peng R., Yi-Huan L., Jia-Wei S., Ragu S., Uin-Ting S. -Characterization of Solvent-Treated PEDOT:PSS Thin Films with Enhanced Conductivities, Polymers 11(134) (2019) 1-10. http://doi.org/10.3390/polym11010134. DOI: https://doi.org/10.3390/polym11010134

Mohsin A., Mieke B., Wim D., Naveen R., Roos P. - Oxygen Gas and UV Barrier Properties of Nano-ZnO-Coated PET and PHBHHx Materials Fabricated by Ultrasonic Spray-Coating Technique, Nanomaterials. 11 (2021) 449. https://doi.org/10.3390/nano11020449. DOI: https://doi.org/10.3390/nano11020449

Jun W., Jinting J., Teppei A., Masaya N., Tohru S., Shijo N., Hirotaka K., Peng H., Katsuaki S. - Silver Nanowire Electrodes: Conductivity Improvement Without Post-treatment and Application in Capacitive Pressure Sensors, Nanomicro Lett. 7 (2015) 51–58. https://doi.org/10.1007/s40820-014-0018-0. DOI: https://doi.org/10.1007/s40820-014-0018-0

Hongshui W., Xueliang Q., Jianguo C., Xiaojian W., Shiyuan D. - Mechanisms of PVP in the preparation of silver nanoparticles, Mater. Chem. Phys. 94 (2005) 449-453. https://doi.org/10.1016/j.matchemphys.2005.05.005. DOI: https://doi.org/10.1016/j.matchemphys.2005.05.005

Long Z., Jiajie L., Yi H., Yanfeng M., Yan W., Yongsheng C. - Size-controlled synthesis of graphene oxide sheets on a large scale using chemical exfoliation, Carbon N. Y. 47 (2009) 3365–3368. http://doi.org/10.1016/j.carbon.2009.07.045. DOI: https://doi.org/10.1016/j.carbon.2009.07.045

Merih Z. Ç., Pinar C. - An amperometric glucose biosensor based on PEDOT PEDOT nanofiber, RSC Adv. 8 (2018) 19724–19731. https://doi.org/10.1039/C8RA01385C. DOI: https://doi.org/10.1039/C8RA01385C

Yuan L., Nanlong H., An efficient hole transport material based on PEDOT dispersed with lignosulfonate: preparation, characterization and performance in polymer solar cells, J. Mater. Chem. A. 3 (2015) 21537–21544. https://doi.org/10.1039/C5TA05167C. DOI: https://doi.org/10.1039/C5TA05167C

Neng Y., Jielin Y., Shuang X., Yuhan K., Tao L., Hongzheng C., Mingsheng X. - Silver nanowires-graphene hybrid transparent conductive electrodes for highly efficient inverted organic solar cells, Nanotechnology 28 (2017) 305402. https://doi.org/10.1088/1361-6528/aa7723. DOI: https://doi.org/10.1088/1361-6528/aa7723

Hui X., Xing Y., Dexi D., Yuzhen Z., and Yuehui W. - Flexible transparent conductive film based on random networks of silver nanowires, Micromachines 9 (2018) 295. https://doi.org/10.3390/mi9060295. DOI: https://doi.org/10.3390/mi9060295

Byung Y. W., Eung S. L., Young J. O., Hyun W. K. - A silver nanowire mesh overcoated protection layer with graphene oxide as a transparent electrode for flexible organic solar cells, RSC Adv 7 (2017) 52914-52922. https://doi.org/10.1039/C7RA10889C. DOI: https://doi.org/10.1039/C7RA10889C

Downloads

Published

30-12-2022

How to Cite

[1]
T. T. H. Nguyen, “Fabrication of flexible multilayer transparent electrode based on silver nanowire, graphene oxide, and poly(3,4-ethylenedioxythiophene): polystyrene sulfonate ”, Vietnam J. Sci. Technol., vol. 60, no. 6, pp. 1067–1077, Dec. 2022.

Issue

Vol. 60 No. 6 (2022)

Section

Materials

License

Creative Commons License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Vietnam Journal of Sciences and Technology (VJST) is an open access and peer-reviewed journal. All academic publications could be made free to read and downloaded for everyone. In addition, articles are published under term of the Creative Commons Attribution-ShareAlike 4.0 International (CC BY-SA) Licence which permits use, distribution and reproduction in any medium, provided the original work is properly cited & ShareAlike terms followed.

Copyright on any research article published in VJST is retained by the respective author(s), without restrictions. Authors grant VAST Journals System a license to publish the article and identify itself as the original publisher. Upon author(s) by giving permission to VJST either via VJST journal portal or other channel to publish their research work in VJST agrees to all the terms and conditions of https://creativecommons.org/licenses/by-sa/4.0/ License and terms & condition set by VJST.

Authors have the responsibility of to secure all necessary copyright permissions for the use of 3rd-party materials in their manuscript.

Crossref
Scopus
Google Scholar
Europe PMC