Study on fabrication and optical properties of monodisperse Ag-Au alloy nanostructure

Le The Tam, Nguyen Thi Ngoc Linh, Saonilan Thapphanya, Dinh Thi Truong Giang
Author affiliations

Authors

  • Le The Tam Vinh University, 182 Le Duan, Vinh City, Nghe An Province, Viet Nam https://orcid.org/0000-0002-1723-0238
  • Nguyen Thi Ngoc Linh Thai Nguyen University of Sciences, Tan Thinh Ward, Thai Nguyen City, Thai Nguyen Province, Viet Nam
  • Saonilan Thapphanya Thai Nguyen University of Sciences, Tan Thinh Ward, Thai Nguyen City, Thai Nguyen Province, Vietnam; Pharmaceutical Factory No 2, Vientiane, Laos
  • Dinh Thi Truong Giang Vinh University, 182 Le Duan, Vinh City, Nghe An Province, Viet Nam https://orcid.org/0009-0002-3574-1207

DOI:

https://doi.org/10.15625/2525-2518/20092

Keywords:

Nanostructure, Ag-A alloy, reduction in organic solvents, monodisperse, optical properties

Abstract

This study addresses challenges in various fields by creating a new method for uniform, size- and composition-controlled Ag-Au alloy nanoparticles in organic solvents. Building on prior research, we demonstrate control over nanoparticle properties by varying complexing agents, surfactants, and reducing agents. Optimal conditions using surfactant SOA and reducing agent TBAB yielded small, monodisperse Ag nanoparticles ideal for alloying with Au. The reaction time significantly impacts final morphology and surface plasmon resonance (SPR) properties of the resultant Ag-Au alloy nanoparticles. Interestingly, Au nanoparticles formed under identical conditions shared a similar size with 60-minute Ag-Au alloys, evidenced by a single SPR peak at 520 nm. This control over Ag-Au nanoalloy composition and size opens doors for promising applications.

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References

Qiao X., Yu K., Xu J., Cai Y., Li Y., Cao H., Lü J. - Engineered nanoscale schwertmannites as Fenton–like catalysts for highly efficient degradation of nitrophenols, Appl. Surf. Sci. 548 (15) (2021) 149248. https://doi.org/10.1016/j.apsusc.2021.149248.

Sareen S., Mutreja V., Pal B., Singh S. - Synthesis of bimetallic Au-Ag alloyed mesocomposites and their catalytic activity for the reduction of nitroaromatics, Appl. Surf. Sci. 435 (30) (2018) 552-562. https://doi.org/10.1016/j.apsusc.2017.11.152.

Heinz M., Srabionyan V. V., Avakyan L. A., Bugaev A. L., Skidanenko A. V., Kaptelinin S. Y., Bugaev L. A. - Formation of bimetallic gold-silver nanoparticles in glass by UV laser irradiation, J. Alloys Compd. 767 (30) (2018) 1253-1263. https://doi.org/10.1016/ j.jallcom.2018.07.183.

Nguyen T. N. L., Le T. T., Nguyen H. D., Nguyen D. V., Phan T.H. T., Bui M. Q., Cao T. A., Nguyen T. S., Le T. L. - Synthesis and properties of Ag-Au alloy nanoparticles with controlled composition for computed tomography imaging applications, ChemNanoMat 10 (5) (2024) e202300619. https://doi.org/10.1002/cnma.202300619.

Liao W., Liu K., Chen Y., Hu J., Gan Y. - Au-Ag bimetallic nanoparticles decorated silicon nanowires with fixed and dynamic hot spots for ultrasensitive 3D SERS sensing, J. Alloys Compd. 868 (2021) 159136. https://doi.org/10.1016/j.jallcom.2021.159136.

Jiao A., Dong X., Zhang H., Xu L., Tian Y., Liu X., Chen M. - Construction of pure worm-like AuAg nanochains for ultrasensitive SERS detection of pesticide residues on apple surfaces, Spectrochimica Acta Part A: Mol. Biomol. Spectrosc. 209 (2019) 241-247. https://doi.org/10.1016/j.saa.2018.10.051.

Arora N., Mehta A., Mishra A., Basu S. - 4-Nitrophenol reduction catalysed by Au-Ag bimetallic nanoparticles supported on LDH: Homogeneous vs. heterogeneous catalysis, Appl. Clay Sci. 151 (2018) 1-9. https://doi.org/10.1016/j.clay.2017.10.015.

Mott D., Thuy N. T. B., Aoki Y., Maenosono S. - Aqueous synthesis and characterization of Ag and Ag-Au nanoparticles: addressing challenges in size, monodispersity and structure, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368 (1927) (2010) 4275-292. https://doi.org/10.1098/rsta.2010.0120.

Wu Y., Jiang P., Jiang M., Wang T., Guo C., Xie S.., Wang Z. - The shape evolution of gold seeds and gold@silver core-shell nanostructures, Nanotechnology 20 (30) (2009) 305602. https://doi.org/10.1088/0957-4484/20/30/305602.

Devarajan S., Vimalan B., Sampath S. - Phase transfer of Au-Ag alloy nanoparticles from aqueous medium to an organic solvent: Effect of aging of surfactant on the formation of Ag-rich alloy compositions, J. Colloid Interface Sci. 278 (1) (2004) 126-132. https://doi.org/10.1016/j.jcis.2004.05.038.

Pal A., Shah, S., Devi S. - Synthesis of Au, Ag and Au-Ag alloy nanoparticles in aqueous polymer solution, Colloids and Surfaces A: Physicochem. Eng. Asp. 302 (1-3) (2007) 51-57. https://doi.org/10.1016/j.colsurfa.2007.01.054.

Wilcoxon J. - Optical absorption properties of dispersed gold and silver alloy nanoparticles, J. Phys. Chem. B 113 (9) (2009) 2647-2656. https://doi.org/10.1021/ jp806930t.

Kim Y., Johnson R. C., Li J., Hupp J. T., Schatz G. C. - Synthesis, linear extinction, and preliminary resonant hyper-Rayleigh scattering studies of gold-core/silver-shell nanoparticles: Comparisons of theory and experiment, Chem. Phys. Lett. 352 (5-6) (2002) 421-428. https://doi.org/10.1016/S0009-2614(01)01506-8.

Ma Yanyun., Li W., Cho E. C., Li Z., Yu T., Zeng J., Xie Z., Xia Younan. - Au@Ag core-shell nanocubes with finely tuned and well-controlled sizes, shell thicknesses, and optical properties, ACS Nano 4 (11) (2010) 6725-6734. https://doi.org/10.1021/nn102237c.

Shankar S. S., Rai A., Ahmad A., Sastry M. - Rapid synthesis of Au, Ag, and bimetallic Au core-Ag shell nanoparticles using Neem (Azadirachta indica) leaf broth, J. Colloid Interface Sci. 275 (2004) 496-502. doi: https://doi.org/10.1016/j.jcis.2004.03.003.

Mallik K., Mandal M., Pradhan N., Pal T. - Seed mediated formation of bimetallic nanoparticles by uv irradiation: A photochemical approach for the preparation of "Core-Shell" type structures, Nano Lett. 1 (6) (2001) 319-322. https://doi.org/10.1021/ nl0100264.

Peng Z., Spliethoff B., Tesche B., Walther T., Kleinermanns K. - Laser-assisted synthesis of Au - Ag alloy nanoparticles in solution, J. Phys. Chem. B 110 (6) (2006) 2549-2554. https://doi.org/10.1021/jp056677w.

Chen H. M., Liu R. S., Jang L. Y., Lee J. F., Hu S. F. - Characterization of core-shell type and alloy Ag/Au bimetallic clusters by using extended X-ray absorption fine structure spectroscopy, Chem. Phys. Lett. 421 (1-3) (2006) 118-123. https://doi.org/10.1016/ j.cplett.2006.01.043.

Nguyen T. N. L., Le T. T., Ngo. T. D., Le. T. T. T., Ha. M. N., Nguyen. D. V., Bui M. Q., Nguyen. T. H. H., Nguyen. H. D., Nguyen. T. T., Le. T. L. - The size-and shape-controlled synthesis of silver nanoparticles by solvothermal method, Vietnam J. Sci. Technol 61 (2) (2023) 246-254. https://doi.org/10.15625/2525-2518/16615.

Poudyal N., Chaubey., Nandwana., Rong C., Yano K., Liu J. P. - Synthesis of FePt nanorods and nanowires by a facile method, Nanotechnology 19 (35) (2008) 355601. https://doi.org/10.1088/0957-4484/19/35/355601.

Yin Y., Alivisatos A. P. - Colloidal nanocrystal synthesis and the organic-inorganic interface, Nature 437 (2005) 664-670. https://doi.org/10.1038/nature04165.

Polavarapu L., Liz-Marzan L. M. - Growth and galvanic replacement of silver nanocubes in organic media, Nanoscale 5 (10) (2013) 4355-4361. https://doi.org/10.1039/ C3NR01244A.

Li. H. J., Hui-Jun L., An-Qi Z., Yang H., Li S., Dong-Jin Q., Meng C. - Large-scale synthesis and self-organization of silver nanoparticles with Tween 80 as a reductant and stabilizer, Nanoscale Res. Lett. 6;7 (1) (2012) 1-13. https://doi.org/10.1186/1556-276x-7-612.

Yamashita Y., Miyahara R., Sakamoto K. - Emulsion and emulsification technology. cosmetic science and technology: Theoretical principles and applications , Elsevier Inc., 2017, pp. 489-506.

Qingbo Z., Jim Y. L., Jun Y. - Size and composition tunable Ag-Au alloy nanoparticles by replacement reactions, Nanotechnol 18 (24) (2007) 245605-245612. https://doi.org/ 10.1088/0957-4484/18/24/245605.

Feldheim J. P. N. - Assembly of phenylacetylene-bridged silver and gold nanoparticle arrays, JACS 122 (16), (2000) 3979-3980. https://doi.org/10.1021/ja000477a.

Pham. T. T. H., Nguyen. D. D., Vu X. H. - Facile synthesis of silver/gold alloy nanoparticles for ultra-sensitive rhodamine B detection, RSC Adv. 11 (35) (2021) 21475-21488. https://doi.org/10.1039/D1RA02576G.

Nguyen. T. N. L., Ngo T. D., Le T. T. T., Le T. T., Nguyen P. H., Nguyen D. V., Ngo T. H., Pham. H. N., Le V. T., Nguyen V. D., Le G., N., Nguyen V. D., Nguyen X. P., Le D. T., Nguyen T. K. T.

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Published

18-06-2024

How to Cite

[1]
T. Le, L. Nguyen, S. Thapphanya, and G. Dinh, “Study on fabrication and optical properties of monodisperse Ag-Au alloy nanostructure”, Vietnam J. Sci. Technol., vol. 62, no. 3, pp. 496–507, Jun. 2024.

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Materials

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