Preparation of hydrogel based on cellulose from sugarcane bagasse

Nguyen Ha Thu; Nguyen Thi Quyen; Vu Anh Duc; Hoang Thu Hang; Do Thu Ha; Tran Ngoc Anh; Nguyen Ngoc Mai

doi:10.15625/2525-2518/17983

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Authors

Nguyen Ha Thu School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam
Nguyen Thi Quyen School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam
Vu Anh Duc School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam
Hoang Thu Hang School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam
Do Thu Ha School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam
Tran Ngoc Anh School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam
Nguyen Ngoc Mai School of Chemistry and Life Science, Hanoi University of Science and Technology, No.1 Dai Co Viet street, Hai Ba Trung district, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/17983

Keywords:

hydrogel, cellulose, sugarcane bagasse

Abstract

In this study, the preparation and characterization of hydrogels from sugarcane bagasse were investigated. The preparation of hydrogels was made with cellulose extracted from sugarcane bagasse, ammonium persulfate as initiator, acrylic acid as monomer and N,N’-Methylenebisacrylamide as crosslinking agent. The characterization of structure and properties of the hydrogels were carried out through Fourier-transform Infrared spectroscopy, Focused Ion Beam Scanning Electron Microscopy, determination of Young’s modulus, tensile strength, elongation at break and Charpy impact, swelling degree and Thermogravimetric Analysis. The optimal condition for the preparation was found at 1.0 g ammonium persulfate/kg cellulose, 1.6 g acrylic acid/kg cellulose and 0.2 g N,N’-Methylenebisacrylamide/kg cellulose. It was found that both anion and cation can be absorbed in the 3D-network of the hydrogel. The highest Young’s modulus, tensile strength, elongation at break and Charpy impact of the obtained hydrogel is 1.3 MPa, 5.2 MPa, 89.0% ad 7.2 kJ/m², respectively. The hydrogel is stable until 110 ^oC. The results show that the obtained hydrogel may be suitable for electrolyte membrane used in battery.

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