Study ability of protection effect of organic acids for multi-metallic anti-corrosion additive system in ethylene glycol-water coolants

Pham Thi Mai Huong, Nguyen Thi Huong
Author affiliations

Authors

  • Pham Thi Mai Huong Faculty of Chemical Technology, Hanoi University of Industry, 298 Cau Dien Street, Bac Tu Liem District, Ha Noi, Viet Nam
  • Nguyen Thi Huong Institute of Chemistry and Material, Academy of Military Science and Technology, 7 Hoang Sam, Cau Giay, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/17071

Keywords:

coolant, corrosion inhibitors, organic acid, multimetallic

Abstract

In this work, the electrochemical behavior of carbon steel, brass, bronze and aluminum alloys in the presence of various important organic acids (sebacic acid (SbA), terephthalic (TPA), 2-ethylhexanoic (E2C6A), and octanoic (C8A)) and the effect that these have on the growth and protectiveness of the alloys have been investigated. The results show that the presence of organic acids in the coolant increases the protective effect of the system by forming a film on the surface of the alloys. The EIS impedance results demonstrate the formation of active and passive protective layers on the surface of the alloys. The results of surveying 04 types of organic acids for the protection of different alloy substrates show that TPA and SbA acid additives are more effective than C8A and E2C5A. The additive C8A not only did not inhibit corrosion but also promoted this process strongly, especially with aluminum alloys and the TPA has the best anti-corrosion effect for steel, followed by C1 copper alloy and aluminum.

Downloads

Download data is not yet available.

References

Argade G., Chilukuri A., Perry J., Viers M., Steenhoek J., Debusk J., Wang C. - Trobaugh C. - Corrosion Behavior of Alloyed Cast Iron in Ethylene Glycol-Based Engine Coolants at Elevated Temperature 11 (2021) 357.

Brycki B., Kowalczyk I., Szulc A., Kaczerewska O., Pakiet M. - Organic Corrosion Inhibitors; Aliofkhazraei, M., Ed., Intechopen, 2018.

Coelho L. B., Lukaczynska-Anderson M., Clerick S., Buytaert G., Lievens S., Terryn H. A. - Corrosion inhibition of AA6060 by silicate and phosphate in automotive organic additive technology coolants, Corrosion Science 199 (2022) 110188.

Gelman D., Lasman I., Elfimchev S., Starosvetsky D., Ein-Eli Y. - Aluminum corrosion mitigation in alkaline electrolytes containing hybrid inorganic/organic inhibitor system for power sources applications, Journal of Power Sources 285 (2015) 100-108.

Jiang H., Yu S., Li W., Yang Y., Yang L., Zhang Z. - Inhibition effect and mechanism of inorganic-organic hybrid additives on three-dimension porous aluminum foam in alkaline Al-air battery, Journal of Power Sources 448 (2020) 227460.

Spicka K. J., Johnston C. J., Jordan M. M., Nguyen L. T., Samaniego S. L., Sutherland L. - The Impact of Organic Acid on Scale Inhibitor/Corrosion Inhibitor Interaction, a Case Study from West Africa, 2011;

Nmai C. K. - Multi-functional organic corrosion inhibitor, Cement and Concrete Composites 26 (2004) 199-207.

Ormellese M., Lazzari L., Goidanich S., Fumagalli G., Brenna A. - A study of organic substances as inhibitors for chloride-induced corrosion in concrete, Corrosion Science 51 (2009) 2959-2968.

Burns Jeffrey M., Sanderson John R., Larkin John M., McCoy David R.- Corrosion-inhibited antifreeze/coolant composition containing aromatic carboxylic acid.EP Patent EP 0487194 A1, 1992/05/27; (1992).

Washington D. A., Miller D. L., Maes J.-P., Van de Ven P., Orth J. E. - Long Life Performance of Carboxylic Acid Based Coolants, SAE Transactions 103 (1994) 787-791.

Maes J. P., Van Neste Walter A.- Corrosion-inhibited antifreeze formulations having monocarboxylic, triazole, and imidazole compounds, US Patent US 5366651 A, 1994/11/22, 1994.

Shah R. K., Subbarao E. C., Mashelkar R. A. - Heat Transfer Equipment Design, Taylor & Francis, 1988.

Worden J. A., Burke J. F., Burke J. P., Cox T. - Development of Aluminum Cooling System Components for a 10.8 Liter Diesel Engine, SAE Transactions 105 (1996) 934-944.

Brycki B., Kowalczyk I., Szulc A., Kaczerewska O., Pakiet M. - Organic Corrosion Inhibitors, IntechOpen: London, 2018.

Downloads

Published

23-02-2024

How to Cite

[1]
Pham Thi Mai Huong and Nguyen Thi Huong, “Study ability of protection effect of organic acids for multi-metallic anti-corrosion additive system in ethylene glycol-water coolants”, Vietnam J. Sci. Technol., vol. 62, no. 1, pp. 48–57, Feb. 2024.

Issue

Section

Materials