Supported liquid membrane with strip dispersion for recovering indium from etching solution of LCD industry: influence of factors on performance

Dang Thi Tuyet Ngan, Tran Trung Kien, Da-Ming Wang
Author affiliations

Authors

  • Dang Thi Tuyet Ngan School of Chemical Engineering, Hanoi University of Science and Technology (HUST), No.1, Dai Co Viet, Ha Noi, Viet Nam
  • Tran Trung Kien School of Chemical Engineering, Hanoi University of Science and Technology (HUST), No.1, Dai Co Viet, Ha Noi, Viet Nam
  • Da-Ming Wang National Taiwan University (NTU), No.1, Sec. 4, Roosevelt Road,Taipei 10617, Taiwan

DOI:

https://doi.org/10.15625/2525-2518/59/1/15569

Keywords:

liquid membrane, indium recovery, etching solution, D2EHPA, some important factors

Abstract

Supported liquid membrane with strip dispersion (SLMSD) is a promising process for metal recovery from e-waste or waste streams because of many advantages such as the ability to combine extraction and stripping into one single step and thus have non-equilibrium mass transfer characteristics and maximum driving force. This paper investigated the effect of important factors on SLMSD performance to recover indium from etching solution such as: pH of feed solution, extractant (Di-(2-ethylhexyl) phosphoric acid (D2EHPA)) concentration, oxalic acid concentration. It was found that 99.5 % In3+ was removed from feed solution in about 20 minutes with high concentration factor (4.5) under suitable conditions (pH 1; 0.6M Di-(2-ethylhexyl) phosphoric acid (D2EHPA), 2 wt% oxalic acid).

Downloads

Download data is not yet available.

References

Porter MC. Handbook of Industrial Membrane Technology. Noyes Publications; 1990.

Ho WSW, Poddar TK. New Membrane Technology for Removal and Recovery of Chromium from Waste Water. Environ Prog. 2001;20(1):44-52. DOI: https://doi.org/10.1002/ep.670200115

Yang J, Ekberg C, Retegan T. Optimization of Indium Recovery and Separation from LCD Waste by Solvent Extraction with Bis ( 2-ethylhexyl ) Phosphate ( D2EHPA ). 2014;2014. DOI: https://doi.org/10.1155/2014/186768

Yen F, Chang T, Laohaprapanon S. Recovery of Indium from LCD waste by solvent extraction and the SLMSD using D2EHPA as the extractant. Solvent Extr Res Dev Japan. 2016;23(1):63-73. DOI: https://doi.org/10.15261/serdj.23.63

Tsai H, Tsai T. Extraction Equilibrium of Indium(III) from Nitric Acid Solutions by Di(2-ethylhexyl)phosphoric Acid Dissolved in Kerosene. Molecules. 2012;17:408-419. DOI:10.3390/molecules17010408. doi:10.3390/molecules17010408 DOI: https://doi.org/10.3390/molecules17010408

Sato T, Sato K. Liquid-liquid extraction of indium ( III ) from aqueous acid solutions by acid organophosphorus compounds. Hydrometallurgy. 1992;30:367-383. DOI: https://doi.org/10.1016/0304-386X(92)90094-G

Sato T. The extraction of Indium ( III ), Lanthanum ( III) and Bismuth (III) from sulphuric acid solutions by Di-(2-ethylhexyl)-phosphoric acid. I inorg nucl Chem. 1975;3(Ill):1485-1488. DOI: https://doi.org/10.1016/0022-1902(75)80795-0

Tsai T, Wu Y. Organic Acid Mixing to Improve ITO Film Etching in Flat Panel Display Manufacturing. J Electrochem Soc. 2006;153(1):C86-C90. doi:10.1149/1.2135221 DOI: https://doi.org/10.1149/1.2135221

Downloads

Published

08-02-2021

How to Cite

[1]
D. T. T. Ngan, T. T. Kien, and D.-M. Wang, “Supported liquid membrane with strip dispersion for recovering indium from etching solution of LCD industry: influence of factors on performance”, Vietnam J. Sci. Technol., vol. 59, no. 1, pp. 90–95, Feb. 2021.

Issue

Section

Environment