Copper triflate catalyzed Baeyer- Villiger oxidation of ketones

Dau Xuan Duc; Nguyen Thi Nguyet

doi:10.15625/2525-2518/57/1/12589

Copper triflate catalyzed Baeyer- Villiger oxidation of ketones

Dau Xuan Duc, Nguyen Thi Nguyet

Author affiliations

Authors

Dau Xuan Duc School of Chemistry, Vinh University, 182 Le Duan, Vinh City, Nghe An, Viet Nam
Nguyen Thi Nguyet School of Chemistry, Vinh University, 182 Le Duan, Vinh City, Nghe An, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/57/1/12589

Keywords:

oxidation, ketone, lactone, ester, catalyst

Abstract

A simple, efficient and eco-friendly method for Baeyer-Villiger oxidation reaction has been developed. The reaction employed m-CPBA as the oxidant with Cu(OTf)₂ catalyst and was carried out in CH₂Cl₂ at room temperature. Nine lactones and ester were obtained in excellent yield (85-94%). Furthermore, the catalyst could be reused twice without considerable loss in activity.

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Published

18-02-2019

How to Cite

Duc, D. X., & Nguyet, N. T. (2019). Copper triflate catalyzed Baeyer- Villiger oxidation of ketones. Vietnam Journal of Science and Technology, 57(1), 76–81. https://doi.org/10.15625/2525-2518/57/1/12589

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Issue

Vol. 57 No. 1 (2019)

Section

Environment

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