Manufacturing of Al-Zr-Si master alloy from zircon concentrate

Huynh Cong Khanh, Ly Thai Phap, Do Thanh Toan
Author affiliations

Authors

  • Huynh Cong Khanh 1Faculty of Materials Technology, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam 2Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh https://orcid.org/0009-0001-7830-1183
  • Ly Thai Phap 1Faculty of Materials Technology, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam 2Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh
  • Do Thanh Toan 1Faculty of Materials Technology, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam 2Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh

DOI:

https://doi.org/10.15625/2525-2518/18562

Keywords:

Al-Zr-Si master alloy, thermal-resistant aluminum alloy, zircon concentrate

Abstract

Aluminum alloy of thermal-resistant aluminum alloy wire for overhead line conductors usually contains zirconium, silicon, iron, and other components. Hence, Al-Zr-Si master alloy can be used to produce thermal-resistant aluminum alloy. In this study, the manufacturing procedure of Al-Zr-Si master alloy from zircon concentrate has been introduced. The zircon concentrate was thoroughly mixed with different amounts of KCl and Na2SiF6 or Na3AlF6, then sintered in the electric muffle furnace at 700oC for 2 hrs with automatic temperature control. The sinter was premixed with NaAlF6 at the 1:1 ratio and dried at 140-160oC to remove the humidity. The powder mixture was added to the aluminum molten at 1200C and then stirred well to ensure proper powder mixing in the melt. After the finish reaction and slag skimming, the melt was taken out of the furnace and poured into the mold. The master alloy was characterized by a Spectrometer, ICP-OES, and optical microscopy.

Downloads

Download data is not yet available.

References

Barsukov V. K., Barsukov E. V., Kurashov D.A., Savchenko V.G. – Thermo-anticorrosive aluminium alloy, RU 2636548 C1, May 25, 2016 (In Russian).

Baranov V. N., Biront V. S., Dovzhenko N. N., Padalka V. A., Sidel’nikov S. B., Trifonenkov L. P., Frolov V. F., Chichuk E. N. – Aluminium alloy, RU 2458151 C1, Dec. 09, 2010 (In Russian).

Morozova A., Mogucheva A., Bukin D., Lukianova O., Korotkova N., Belov N., Kaibyshev R. - Effect of Si and Zr on the Microstructure and Properties of Al-Fe-Si-Zr Alloys, Metals 7 (11) (2017) 495, doi:10.3390/met7110495.

Nokhrin A. V., Nagicheva G. S., Chuvil’deev V. N., Kopylov V. I., Bobrov A. A., Tabachkova N. Y. - Effect of Er, Si, Hf and Nb Additives on the Thermal Stability of Microstructure, Electrical Resistivity and Microhardness of Fine-Grained Aluminum Alloys of Al-0.25%Zr, Materials 16 (5) (2023) 2114, https://doi.org/10.3390/ma16052114.

Belov N.A., Korotkova N.O., Alabin A.N., Mishurov S.S. - Effect of silicon addition on specific electrical resistivity and hardness of Al–1%Fe–0,3%Zr alloy, Izvestiya, Non-Ferrous Metallurgy, (2) (2018) 50–58, DOI dx.doi.org/10.17073/0021-3438-2018-2-50-58 (In Russian).

Morozova A. I., Mogucheva A. A., Tagirov D. V., Kajbyshev R. O., “Aluminum-zirconium alloy”, RU 2696797 C2, Oct. 04, 2017 (In Russian).

Trukhov A.P.. Malyarov A.I. – Casting alloys and melting, Publishing center “Academy”, Moscow, 2004, pp. 312-316 (In Russian).

Napalkov V. I., Makhov S,V. – Alloying and modification of aluminum and magnesiun, MISIS, Moscow 2002, pp. 99-105, 210-217 (In Russian).

Decision No. 1546/QD-TTg dated September 3, 2013, approving the zoning plan for exploration, extraction, processing and exploitation of titan ores by 2020 with vision to 2030, (in Vietnamese).

Lyakisheb N. P., Pliner Yu. L. Ignatenko G. F., Lappo S. I. – Aluminothermy, Metallurgy, Moscow, 1978, pp. 9-19 (In Russian).

Zelikman A. N., Korshuhov B. G. – Metallurgy of rare metals, Metallurgy, Moscow, 1991, pp. 188-190 (In Russian)

Shakhno I. V., Shevtsova Z. N., Fedorov P. I., Korovin S. S./Edited by Bolshakova K. A. – Chemistry and technology of rare and scattered elements, Vol. 2, Higher School, Moscow, 1976, pp. 322-323 (In Russian)

Mondolfo L. F. - Aluminum Alloys: Structure and Properties, Translated from the English, Metallurgy, Moscow, 1979, p. 350 (In Russian).

Abdelaziz M. H., Doty H. W., Valtierra S., Samuel F. H. - Mechanical performance of Zr-containing 354-type Al-Si-Cu-Mg cast alloy: Role of additions and heat treatment, Advances in Materials Science and Engineering, (4) (2018) 1-17, https://doi.org/10.1155/2018/5715819

Vorob'ev A. S. , Suzdaltsev A. V., Pershin P. S., Galashev A. E., Zaikova Yu. P.

- Structure of MF-AlF3-ZrO2 (M = K, Na, Li) ionic melts. Journal of Molecular Liquids, 299 (2020) 112241, https://doi.org/10.1016/j.molliq.2019.112241.

Takayuki H., Hiroshi O. and Mitsuhiro H. - Thermodynamic analysis of the Al-Si-Zr ternary system, High Temperature Materials and Processes, 29 (5-6) (2010) 347-371, https://doi.org/10.1515/HTMP.2010.29.5-6.347.

Habashi F. (Ed.) – Handbook of extractive metallurgy, Wiley-VCH, 1997, p. 1116 (Vol II), 1454 (Vol. III), 1970 (Vol IV).

Downloads

Published

24-07-2024

How to Cite

[1]
H. C. Khanh, L. T. Phap, and D. T. Toan, “Manufacturing of Al-Zr-Si master alloy from zircon concentrate”, Vietnam J. Sci. Technol., vol. 61, no. 4, Jul. 2024.

Issue

Section

Materials