Conceptual Design for Synthesis of Benzaldehyde from Natural Cinnamomum Cassia Oil: Experiments and Simulation

Nguyen Trung Dung, Phan Ngoc Quang, Nguyen Vân-Anh, Ta Hong Duc, Xuan-Mi Meyer, Jean Francois Blanco, Patrick Cognet, Michel Meyer, Cao Hong Ha
Author affiliations

Authors

  • Nguyen Trung Dung School of Chemical Engineering, Hanoi University of Science and Technology, No. 1 Dai Co Viet, Hai Ba Trung, Ha Noi, Viet Nam
  • Phan Ngoc Quang School of Chemical Engineering, Hanoi University of Science and Technology, No. 1 Dai Co Viet, Hai Ba Trung, Ha Noi, Viet Nam
  • Nguyen Vân-Anh School of Chemical Engineering, Hanoi University of Science and Technology, No. 1 Dai Co Viet, Hai Ba Trung, Ha Noi, Viet Nam
  • Ta Hong Duc School of Chemical Engineering, Hanoi University of Science and Technology, No. 1 Dai Co Viet, Hai Ba Trung, Ha Noi, Viet Nam
  • Xuan-Mi Meyer ENSIACET – INP de Toulouse, Laboratoire de Genie Chimique, Universite de Toulouse, UMR CNRS 5503, 4 Allee Emile Monso, BP 44362, 31432 Toulouse, France
  • Jean Francois Blanco ENSIACET – INP de Toulouse, Laboratoire de Genie Chimique, Universite de Toulouse, UMR CNRS 5503, 4 Allee Emile Monso, BP 44362, 31432 Toulouse, France
  • Patrick Cognet ENSIACET – INP de Toulouse, Laboratoire de Genie Chimique, Universite de Toulouse, UMR CNRS 5503, 4 Allee Emile Monso, BP 44362, 31432 Toulouse, France
  • Michel Meyer ENSIACET – INP de Toulouse, Laboratoire de Genie Chimique, Universite de Toulouse, UMR CNRS 5503, 4 Allee Emile Monso, BP 44362, 31432 Toulouse, France
  • Cao Hong Ha School of Chemical Engineering, Hanoi University of Science and Technology, No. 1 Dai Co Viet, Hai Ba Trung, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/17982

Keywords:

design and simulation, separation and purification, benzaldehyde, trans-cinnamaldehyde, cinnamomum cassia oil

Abstract

The results on the synthesis of natural benzaldehyde from trans-cinnamaldehyde in natural cinnamon essential oil are presented in this study. The synthetic experiments were carried out to get the primary input parameters for design and simulation, including reaction and extraction steps. The conversion of trans-cinnamaldehyde to benzaldehyde were achieved the highest conversion rate of 33.5 %, and the initial quantity of ethyl acetate solvent was 3825 kg/h used the Aspen Plus® software. The optimal stage of extraction was six, and the optimal quantity of ethyl acetate solvent was 3695 kg/h. In the distillation stage, a two-column design was proposed. The first column was for ethyl acetate solvent removal, whereas the second one was used for purifying the target product (benzaldehyde). The operating conditions of the columns were optimized not only based on the vapor feed but also the equipment cost to minimize the investment budget. The optimal parameters for the first column (D-1) and the second column (D-2) were the number of theoretical plates of 7 (D-1), 11 (D-2); the feed position of 3 (D-1), 5 (D-2); the real reflux ratio of 0.11 (D-1), 2.59 (D-2); and the distillate for feed fraction of 0.9536 (D-1), 0.2171 (D-2), respectively.

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Published

01-03-2024

How to Cite

[1]
T. D. Nguyen, “Conceptual Design for Synthesis of Benzaldehyde from Natural Cinnamomum Cassia Oil: Experiments and Simulation”, Vietnam J. Sci. Technol., vol. 62, no. 4, pp. 635–647, Mar. 2024.

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Section

Natural Products