Conceptual Design for Synthesis of Benzaldehyde from Natural Cinnamomum Cassia Oil: Experiments and Simulation
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https://doi.org/10.15625/2525-2518/17982Keywords:
design and simulation, separation and purification, benzaldehyde, trans-cinnamaldehyde, cinnamomum cassia oilAbstract
The results on the synthesis of natural benzaldehyde from trans-cinnamaldehyde in natural cinnamon essential oil are presented in this study. The synthetic experiments were carried out to get the primary input parameters for design and simulation, including reaction and extraction steps. The conversion of trans-cinnamaldehyde to benzaldehyde were achieved the highest conversion rate of 33.5 %, and the initial quantity of ethyl acetate solvent was 3825 kg/h used the Aspen Plus® software. The optimal stage of extraction was six, and the optimal quantity of ethyl acetate solvent was 3695 kg/h. In the distillation stage, a two-column design was proposed. The first column was for ethyl acetate solvent removal, whereas the second one was used for purifying the target product (benzaldehyde). The operating conditions of the columns were optimized not only based on the vapor feed but also the equipment cost to minimize the investment budget. The optimal parameters for the first column (D-1) and the second column (D-2) were the number of theoretical plates of 7 (D-1), 11 (D-2); the feed position of 3 (D-1), 5 (D-2); the real reflux ratio of 0.11 (D-1), 2.59 (D-2); and the distillate for feed fraction of 0.9536 (D-1), 0.2171 (D-2), respectively.
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References
Guiné R. P., Florença S. G., Barroca M. J., Anjos O. - The link between the consumer and the innovations in food product development, Foods 9 (2020) 1317.
Kumar S., Dhir A., Talwar S., Chakraborty D., Kaur P. - What drives brand love for natural products? The moderating role of household size, Journal of Retailing and Consumer Services 58 (2021) 102329.
Buck Keith T., Boeing Anthony J., Dolfini Joseph E. - Method of producing benzaldehyde.US Patent US 4673766 A, 1987/06/16, 1987.
Wang S. Y., Chen P. F., Chang S. T. - Antifungal activities of essential oils and their constituents from indigenous cinnamon (Cinnamomum osmophloeum) leaves against wood decay fungi, Bioresource Technology 96 (2005) 813-818.
Wright P., Abbot J. - The oxidation of cinnamaldehyde with alkaline hydrogen peroxide, International Journal of Chemical Kinetics 25 (1993) 901-911.
Yang Z., Ji H. - 2-Hydroxypropyl-β-cyclodextrin Polymer as a Mimetic Enzyme for Mediated Synthesis of Benzaldehyde in Water, ACS Sustainable Chemistry & Engineering 1 (2013) 1172-1179.
Yang Z., Ji H. - Synergistic effect of hydrogen bonding mediated selective synthesis of benzaldehyde in water, Chinese Journal of Catalysis 35 (2014) 590-598.
Yadav G. D., Fernandes G. P. - Selective synthesis of natural benzaldehyde by hydrolysis of cinnamaldehyde using novel hydrotalcite catalyst, Catalysis Today 207 (2013) 162-169.
Li H., Meng Y., Shu C., Li X., Kiss A. A., Gao X. - Innovative Reactive Distillation Process for the Sustainable Synthesis of Natural Benzaldehyde, ACS Sustainable Chemistry & Engineering 6 (2018) 14114-14124.
Chen H., Ji H. - Alkaline hydrolysis of cinnamaldehyde to benzaldehyde in the presence of β-cyclodextrin, AIChE Journal 56 (2010) 466-476.
Luyben W. L. - Distillation design and control using Aspen simulation, John Wiley & Sons, 2013.
Chen Q., Feng L. - Simulation Study of Citronellol-geraniol Rectification Tower Based on Aspen Plus Software, MATEC Web Conf. 267 (2019) 02008.
Haydary J. - Chemical process design and simulation: Aspen Plus and Aspen Hysys applications, John Wiley & Sons, 2019.
Dung N. T., Ha C. H., Meyer X. M., Meyer M., Blanco J. F., Cognet P. - Comparing sustainable methods for synthesis of natural benzaldehyde from trans-cinnamaldehyde: Experimental analysis, Vietnam Journal of Chemistry 58 (2020) 471-476.
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