Synthesizing and investigating the electrical properties of carbonized metal–organic frameworks

Huy Quoc Tran; Huong Thi  Diem Nguyen; Hoang Van Nguyen; Nhung Thi Tran; Tung Thanh Nguyen; Long Hoang Ngo; Thach Ngoc Tu

doi:10.15625/2525-2518/16311

Author affiliations

Authors

Huy Quoc Tran HCMC University of Technology and Education, 01 Vo Van Ngan Street, Thu Duc District, Ho Chi Minh City, Viet Nam
Huong Thi Diem Nguyen University of Science, Vietnam National University (VNU-HCM), 227 Nguyen Van Cu street, district 5, Ho Chi Minh city, Viet Nam
Hoang Van Nguyen University of Science, Vietnam National University (VNU-HCM), 227 Nguyen Van Cu street, district 5, Ho Chi Minh city, Viet Nam
Nhung Thi Tran HCMC University of Technology and Education, 01 Vo Van Ngan Street, Thu Duc District, Ho Chi Minh City, Viet Nam
Tung Thanh Nguyen NTT Hi-Tech Institute, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, District 4, Ho Chi Minh City, Viet Nam
Long Hoang Ngo NTT Hi-Tech Institute, Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, District 4, Ho Chi Minh City, Viet Nam
Thach Ngoc Tu Nguyen Tat Thanh University, 300A Nguyen Tat Thanh Street, District 4, Ho Chi Minh City, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/16311

Keywords:

Metal organic framework, carbonization, electrode, electrocatalysis, supercapacitor

Abstract

The metal–organic frameworks (MOFs)such as VNU-20, ZIF-8, ZIF-67, MOF-199, and MIL-53 were synthesized and carbonized. The obtained MOFs and their carbonized analogs were characterized by powder X-ray diffraction. Subsequently, the carbonized materials were mixed with poly(vinylidene fluoride-co-hexafluoroproplylene)/(1-Methyl-2- Pyrrolidinone) at 5 wt% and cast on glassy carbon electrodes for subsequent analyses. The cyclic voltammetry (CV) measurements of carbonized samples were carried out. The resulting CV scans indicate the reversible CV curves of carbonized VNU-20 electrodes through the reversible redox oxidation reactions between Fe^II and Fe^III. Alongside this, the carbonized VNU-20 is found to have a comparable capacitance with that of carbonized ZIF-67, which is among the highest capacitance materials recorded in the literature for the same class of materials. Although further experiments need to be carried out for the optimization, our analysis initially reveals the promising properties of the carbonized VNU-20 electrode for electro-catalysis and the supercapacitor.

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