The geochemical gas field in surface sediments in the Southwest sub-basin of East Vietnam Sea: distribution, origin, and comparative features with other regions of Western East Vietnam Sea

Le Duc Luong, Nguyen Hoang, Anatoly Obzhirov, Ryuichi Shinjo, Renat B. Shakirov
Author affiliations

Authors

  • Le Duc Luong Institute of Geological Sciences, VAST, Vietnam
  • Nguyen Hoang Institute of Geological Sciences, VAST, Vietnam; Graduate University of Science and Technology, VAST, Vietnam
  • Anatoly Obzhirov V. I. Il’ichev Pacific Oceanological Institute, FEB RAS, Vladivostok, Russia
  • Ryuichi Shinjo Research Institute for Humanity and Nature, 457-4 Motoyama, Kamigamo, Kita-Ku, Kyoto 603-8047, Japan; Department of Physics and Earth Sciences, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan
  • Renat B. Shakirov V. I. Il’ichev Pacific Oceanological Institute, FEB RAS, Vladivostok, Russia

DOI:

https://doi.org/10.15625/1859-3097/17398

Keywords:

East Vietnam Sea, hydrocarbon, methane, background concentrations.

Abstract

We analyzed 39 gas samples, including carbon dioxide, hydrocarbon gases C1–C4, hydrogen, and helium, in surface sediment from 19 gravity cores collected from the SW sub-basin of the East Vietnam Sea (EVS) using the headspace and vacuum degassing methods. Based on the result, we discussed the distribution and origin of gases in the southwest sub-basin EVS surface sediments. The sediments are mostly clay and silty clay containing methane ranging from 0.5–440 ppm. The anomalous concentrations of methane, helium, and hydrogen occur along the continental slope in the Nam Con Son basin of Southwest EVS. Methane is the dominant gas compared to other detected hydrocarbon gases, including ethylene, propane, and butane. Based on comparative results, the background methane concentrations in surface sediments decrease from South to North, from the southwestern sub-basin of the East Vietnam Sea to the Phu Khanh and the Red river basins. We propose the presence of a large-scale degassing zone of hydrocarbon gases and discuss the gases’ origin in surface sediments based on hydrocarbon gas ratios, carbon isotope compositions of carbon dioxide and methane, and the relationship between geochemical characteristics of surface sediments and fault system, and surface sediment gases.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

Li, C. F., Lin, J., and Kulhanek, D. K. the Expedition 349 Scientists, 2015. South China Sea tectonics. Proceedings of the International Ocean Discovery Program (IODP). 2015.3. 30, 349: 1, 300.

Tseng, H. C., Chen, C. T. A., Borges, A. V., DelValls, T. A., and Chang, Y. C., 2017. Methane in the South China Sea and the Western Philippine Sea. Continental Shelf Research, 135, 23–34.

Zhang, M., Lu, H., Guan, H., Liu, L., Wu, D., and Wu, N., 2018. Methane seepage intensities traced by sulfur isotopes of pyrite and gypsum in sediment from the Shenhu area, South China Sea. Acta Oceanologica Sinica, 37(7), 20–27.

Shakirov, R. B., Lan, N. H., Yatsuk, A., Mishukova, G., and Shakirova, M., 2018. Methane flux into the atmosphere in the Bien Dong (East Sea of Vietnam). Vietnam Journal of Marine Science and Technology, 18(3), 250–255.

Shakirov, R. B., Yatsuk, A. V., Mishukova, G. I., Obzhirov, A. I., Yugai, I. G., Cuong, D. H., Lan, N. H., Legkodimov, A. A., and Shakirova, M. V., 2019. Methane flux into the atmosphere in the South China Sea. In Doklady Earth Sciences (Vol. 486, No. 1, pp. 533–536). Pleiades Publishing.

Luong, L. D., Shakirov, R. B., Hoang, N., Shinjo, R., Obzhirov, A., Syrbu, N., and Shakirova, M., 2019. Features in REE and methane anomalies distribution in the East China Sea water column: a comparison with the South China Sea. Water Resources, 46(5), 807–816.

Luong, L. D., Obzhirov, A. I., Hoang, N., Shakirov, R. B., Anh, L. D., Syrbu, N. S., Tuan, D. M., Tao, N. V., Huong, T. T., Cuong, D. H., Kholmogorov, A. O., Binh, P. V., Mishukova, O. V., and Eskova, A. I., 2021. Distribution of Gases in Bottom Sediments of the Southwestern sub-basin South China Sea (Bien Dong). Russian Journal of Pacific Geology, 15(2), 144–154.

Shakirov, R. B., Obzhirov, A., Shakirova, M., Jin, Y. K., and Trung, N. N., 2017. Concept of Eastern Asia gas hydrate belt. In Tottori International Forum on Methane Hydrate (pp. 94–95).

Shakirov, R. B., Cuong, D. H., Obzhirov, A. I., Valitov, M. G., Lee, N. S., Legkodimov, A. A., Kalgin, V. Yu., Yeskova, A. I., Proshkina, Z. N., Telegin, Yu. A., Storozhenko, A. V., Ivanov, M. V., Pletnev, S. P., Sedin, V. T., Bulanov, A. V., Shvalov, D. A., Lipinskaya, N. A., Bovsun, M. A., Makseev, D. S., Thanh, N. T., Anh, L. D., and Luong, L. D., 2021. Integrated Geological–Geophysical and Oceanographic Research in the South China Sea: Cruise 88 of the R/V “Akademik MA Lavrentyev”. Oceanology, 61(1), 147–149.

Taylor, B., and Hayes, D. E., 1980. The tectonic evolution of the South China Basin. Washington DC American Geophysical Union Geophysical Monograph Series, 23, 89–104.

Taylor, B., and Hayes, D. E., 1983. Origin and history of the South China Sea basin. Washington DC American Geophysical Union Geophysical Monograph Series, 27, 23–56.

Briais, A., Patriat, P., and Tapponnier, P., 1993. Updated interpretation of magnetic anomalies and seafloor spreading stages in the South China Sea: Implications for the Tertiary tectonics of Southeast Asia. Journal of Geophysical Research: Solid Earth, 98(B4), 6299–6328.

PetroVietnam, 2005. Geology and oil and gas resources of Vietnam. 526 p.

Li, L., and Clift, P. D., 2013. The sedimentary, magmatic and tectonic evolution of the southwestern South China Sea revealed by seismic stratigraphic analysis. Marine Geophysical Research, 34(3), 341–365.

Ding, W., Li, J., Clift, P. D., and Expedition, I. O. D. P., 2016. Spreading dynamics and sedimentary process of the Southwest Sub-basin, South China Sea: constraints from multi-channel seismic data and IODP Expedition 349. Journal of Asian Earth Sciences, 115, 97–113.

Van Phach, P., Van Tri, T., Trung, N. N., and Anh, L. D., 2018. The Geological Structure of the Southwestern end of the East Sea. Proceeding of the 15th regional congress on Geology, Mineral and Energy resources of Southeast Asia (GEOSEA XV), pp. 238–241.

Phuong, N. H., and Truyen, P. T., 2015. Probabilistic seismic hazard maps of Vietnam and the East Vietnam Sea. Vietnam Journal of Marine Science and Technology, 15(1), 77–90.

Liu, Z., Zhao, Y., Colin, C., Stattegger, K., Wiesner, M. G., Huh, C. A., Zhang, Y., Li, X., Sompongchaiyakul, P., You, C.-F., Huang, C.-Y., Liu, J. T., Siringan, F. P., Le, K. P., Sathiamurthy, E., Hantoro, W. S., Liu, J., Tuo, S., Zhao, S., Zhou, S., He, Z., Wang, Y., Bunsomboonsakul, S., and Li, Y., 2016. Source-to-sink transport processes of fluvial sediments in the South China Sea. Earth-Science Reviews, 153, 238–273.

Milliman, J. D., and Meade, R. H., 1983. World-wide delivery of river sediment to the oceans. The Journal of Geology, 91(1), 1–21.

Schimanski, A., and Stattegger, K., 2005. Deglacial and Holocene evolution of the Vietnam shelf: stratigraphy, sediments and sea-level change. Marine Geology, 214(4), 365–387.

Wang, P., and Li, Q. (Eds.), 2009. The South China Sea: Paleoceanography and Sedimentology (Vol. 13). Springer Science & Business Media. 512 p.

Shinjo, R., Shakirov, R. B., and Obzhirov, A., 2021. Chemical, mineralogical, and physicochemical features of surface saline muds from Southwestern sub-basin of the East Vietnam Sea: Implication for new peloids. Vietnam Journal of Earth Sciences, 43(4), 496–508.

Nguyen, H., Shinjo, R., Tran, T. H., Le, D. L., and Le, D. A., 2021. Mantle geodynamics and source domain of the East Vietnam Sea opening-induced volcanism in Vietnam and neighboring regions. Vietnam Journal of Marine Science and Technology, 21(4), 393–417.

Reimann, C., Filzmoser, P., and Garrett, R. G., 2005. Background and threshold: critical comparison of methods of determination. Science of The Total Environment, 346(1–3), 1–16.

Folk, R. L., 1974. Petrology of sedimentary rocks. Hemphill Publishing Company, Austin, Texas 78703.

Anders, E., and Grevesse, N., 1989. Abundances of the elements: Meteoritic and solar. Geochimica et Cosmochimica acta, 53(1), 197–214.

McLennan, S. M., Hemming, S., McDaniel, D. K., and Hanson, G. N., 1993. Geochemical approaches to sedimentation, provenance, and tectonics. Special Papers-Geological Society of America, 284, 21–40.

Taylor, S. R., and McLennan, S. M., 1997. The origin and evolution of the Earth's continental crust. AGSO Journal of Australian Geology and Geophysics, 17, 55–62.

Center for Geological Information, Archives and Journals, General Department of Geology and Minerals of Vietnam, Ministry of Natural Resources and Environment, 2010. Geological map, geological resources of Vietnam and adjacent sea regions, scale 1:1.000.000.

Nghi, T., 2010. Sedimentology in marine geology and petroleum. Vietnam National University Press, Hanoi, 326 p.

Obzhirov, A., Shakirov, R., Salyuk, A., Suess, E., Biebow, N., and Salomatin, A., 2004. Relations between methane venting, geological structure and seismo-tectonics in the Okhotsk Sea. Geo-marine letters, 24(3), 135–139.

Tien, H.D, 2006. Petroleum geology and methods of prospecting, exploration, monitoring oil and gas field. Vietnam National University Ho Chi Minh City Press, 536 p.

Shakirov, R. B., Valitov, M. G. Lee, N. S., Hoang, N., and Phach, P. V., 2021. Monograph: Geologic-geophysical and oceanographic research of the western South China sea and adjacent continent (on results of the RV “Akademik M.A. Lavrentyev” cruise 88 and coastal surveys 2010–2020). Moscow, GEOS, 412 p.

Bernard, B. B., Brooks, J. M., and Sackett, W. M., 1976. Natural gas seepage in the Gulf of Mexico. Earth and Planetary Science Letters, 31(1), 48–54.

Yatsuk, A., Shakirov, R., Gresov, A., and Obzhirov, A., 2020. Hydrocarbon gases in seafloor sediments of the TATAR strait, the northern sea of Japan. Geo-Marine Letters, 40(4), 481–490.

Tien, H. D., Chat, H. C., Dung, N. N., and Anh, N. N., 2008. Comparison of geochemical characteristics of parent rock and petroleum in two sedimentary basins Cuu Long and Nam Con Son. Science & Technology Development, 11(11), 106–118.

Claypool, G. E., Presley, B. J., and Kaplan, I. R., 1973. Gas analyses in sediment samples from Legs 10, 11, 13, 14, 15, 18, and 19. In Creager, J. S., Scholl, D. W, et al., Init. Repts. DSDP, 19: Washington (U.S. Govt. Printing Office), 879–884.

Cline, J. D., and Holmes, M. L., 1977. Submarine seepage of natural gas in Norton Sound, Alaska. Science, 198(4322), 1149–1153.

Kvenvolden, K. A., and Redden, G. D., 1980. Hydrocarbon gas in sediment from the shelf, slope, and basin of the Bering Sea. Geochimica et Cosmochimica Acta, 44(8), 1145–1150.

Kvenvolden, K. A., Vogel, T. M., and Gardner, J. V., 1981. Geochemical prospecting for hydrocarbons in the outer continental shelf, southern Bering Sea, Alaska. Journal of Geochemical Exploration, 14, 209–219.

Claypool, G. E., and Kvenvolden, K. A., 1983. Methane and other hydrocarbon gases in marine sediment. Annual Review of Earth and Planetary Sciences, 11, 299–327.

Kvenvolden, K. A., 1988. Hydrocarbon gas in sediment of the southern Pacific Ocean. Geo-marine letters, 8(3), 179–187.

Pimmel, A., and Claypool, G., 2001. Introduction to shipboard organic geochemistry on the JOIDES Resolution. ODP Technical Note, 30, 29 pages. Address: http://www-odp.tamu.edu/publications/tnotes/tn30/index.htm.

Hachikubo, A., Krylov, A., Sakagami, H., Minami, H., Nunokawa, Y., Shoji, H., Matveeva, T., Jin, Y. K., and Obzhirov, A., 2010. Isotopic composition of gas hydrates in subsurface sediments from offshore Sakhalin Island, Sea of Okhotsk. Geo-Marine Letters, 30(3), 313–319.

Syrbu, N. S., Cuong, D. H., Iakimov, Т. S., Kholmogorov, A. О., Telegin, Y. А., and Tsunogai, U., 2021. Geological features for the formation of gas-geochemical fields, including helium and hydrogen, in the water and sediments at the Vietnamese part of the South-China Sea. Georesursy = Georesources, 23(3), 132–142.

Golding, S. D., Boreham, C. J., and Esterle, J. S., 2013. Stable isotope geochemistry of coal bed and shale gas and related production waters: A review. International Journal of Coal Geology, 120, 24–40.

Dutta, S., Ghosh, S., and Varma, A. K., 2021. Methanogenesis in the Eocene Tharad lignite deposits of Sanchor Sub-Basin, Gujarat, India: Insights from gas molecular ratio and stable carbon isotopic compositions. Journal of Natural Gas Science and Engineering, 91, 103970.

Shakirov, R. B., Sorochinskaja, A. V., Syrbu, N. S., Tsunogai, U., and Yen, T. H., 2020. Gas-geochemical studies of gas fields and increased metal concentrations in the East Siberian Sea. Vietnam Journal of Earth Sciences, 42(4), 395–410.

O’nions, R. K., and Oxburgh, E. R., 1983. Heat and helium in the Earth. Nature, 306(5942), 429–431.

Shakirov, R. B., Syrbu, N. S., and Obzhirov, A. I., 2016. Distribution of helium and hydrogen in sediments and water on the Sakhalin slope. Lithology and mineral resources, 51(1), 61–73.

Telegin, Y. A., Obzhirov, A. I., and Shakirov, R. B., 2021. Gasgeochemical fields in the water column. Monograph: Geologic-geophysical and oceanographic research of the western South China sea and adjacent continent (on results of the RV “Akademik M.A. Lavrentyev” cruise 88 and coastal surveys 2010–2020). Moscow, GEOS, 412 p.

Akulichev, V. A., Obzhirov, A. I., Shakirov, R. B., Van Phach, P., Trung, N. N., Hung, D. Q., Mal’tseva, E. V., Syrbu, N. S., Polonik, N. S., and Polonik, N. S., 2015. Anomalies of natural gases in the Gulf of Tonkin (South China Sea). In Doklady Earth Sciences (Vol. 461, No. 1, pp. 203–208). Springer.

Le, D. A., Trung, N. N., Phach, P. V., Hung, D. Q., Diep, N. V., Nam, B. V., Shakirov, R. B., Obzhirov, A. I., Ugai, I. G., Mal’tseva, E. V., Telegin, Yu. A., and Syrbu, N. S., 2014. Characteristics of helium, methane and hydrogen distribution and their relationship with fault systems in the north of the Gulf of Tonkin. Vietnam Journal of Marine Science and Technology, 14(4A), 78–89.

Hung, D. Q., Shakirov, R., Iugai, I., Van Diep, N., Dong, M. D., Van Nam, B., and Telegin, Y., 2019. A study on the relationship between gas-geochemical field and tectonic fault activities in the rivermouth area of northwestern Gulf of Tonkin. Vietnam Journal of Marine Science and Technology, 19(2), 191–198.

Downloads

Published

28-12-2022

How to Cite

Le, D. L., Nguyen, H., Obzhirov, A., Shinjo, R., & Shakirov, R. B. (2022). The geochemical gas field in surface sediments in the Southwest sub-basin of East Vietnam Sea: distribution, origin, and comparative features with other regions of Western East Vietnam Sea. Vietnam Journal of Marine Science and Technology, 22(4), 337–362. https://doi.org/10.15625/1859-3097/17398

Issue

Section

Articles