Electrochemical Performance of \(\text{Na}_{0.44}\text{MnO}_{2}\)  Synthesized by Hydrothermal Method Using as a Cathode Material for Sodium Ion Batteries

Tan Anh Ta; Long Duy Pham; Hieu Sy Nguyen; Chung Vu Hoang; Chi Ha Le; Chien Tran Dang; Hoa Thi Thu Nguyen; Nghia Van Nguyen

doi:10.15625/0868-3166/27/2/9631

Electrochemical Performance of \(\text{Na}_{0.44}\text{MnO}_{2}\) Synthesized by Hydrothermal Method Using as a Cathode Material for Sodium Ion Batteries

Tan Anh Ta, Long Duy Pham, Hieu Sy Nguyen, Chung Vu Hoang, Chi Ha Le, Chien Tran Dang, Hoa Thi Thu Nguyen, Nghia Van Nguyen

Author affiliations

Authors

Tan Anh Ta
Long Duy Pham
Hieu Sy Nguyen
Chung Vu Hoang
Chi Ha Le
Chien Tran Dang
Hoa Thi Thu Nguyen
Nghia Van Nguyen Hanoi Architectural University

DOI:

https://doi.org/10.15625/0868-3166/27/2/9631

Keywords:

cathode materials, hydrothermal method, Na0.44MnO2, sodium ion battery

Abstract

Orthorhombic Na_0.44MnO₂ with an S-shape tunnel structure was successfully synthesized by a hydrothermal method. The Na_0.44MnO₂material has lattice parameters of a = 9.0842 Å, b = 26.2889 Å, and c = 2.8245 Å. Scanning electron microscope analysis reveals that the morphologies of Na_0.44MnO₂ consist of Na_0.44MnO₂ nanowires with diameters of about 30-50 nm and Na_0.44MnO₂ particles with the size in the range of 200 to 500 nm. The first charge and discharge capacities of Na_0.44MnO₂ cathode, at 0.1 C between 2.0-4.0 V, are 66.2 mAh g^-1 and 62.7 mAh g^-1, respectively. The Na_0.44MnO₂ has an excellent cycle stability with 85.3% of capacity retention over 50 cycles. The coulombic efficiency of Na_0.44MnO₂ material is approximately 90% after 70 cycles. It is suggested that the structure of Na_0.44MnO₂ is stable during cycling and Na_0.44MnO₂ can be a promising cathode material for sodium ion batteries.

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Published

24-08-2017

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[1]

T. A. Ta, “Electrochemical Performance of \(\text{Na}_{0.44}\text{MnO}_{2}\) Synthesized by Hydrothermal Method Using as a Cathode Material for Sodium Ion Batteries”, Comm. Phys., vol. 27, no. 2, p. 143, Aug. 2017.

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