Dielectric and Relaxor Ferroelectric Properties in \(\text{PZT-PMnN-PSbN}\) Ceramics

Than Trong Huy, Nguyen Dinh Tung Luan, Truong Van Chuong, Le Van Hong
Author affiliations

Authors

  • Than Trong Huy Hue University
  • Nguyen Dinh Tung Luan Industrial College of Hue
  • Truong Van Chuong Hue Science University
  • Le Van Hong Institute of Material Science

DOI:

https://doi.org/10.15625/0868-3166/22/3/2263

Keywords:

relaxor ferroelectric, PZT-PMnN-PSbN, Columbite precursor rout, diffuse phase transition, nanopolar regions

Abstract

The rhombohedral perovskite 0.9Pb(Zr0.5Ti0.5)O3 – xPb(Mn1/3Nb1/3)O3 – (0.1-x)Pb(Sb1/2Nb1/2)O3, x = 0.05; 0.06; 0.07; 0.08; 0.09; 0.1 (PZT – PMnN – PSbN) ceramic was synthesized by the Columbite precursor rout. The temperature dependence of dielectric constant and its loss in a frequency region of 0.1 kHz – 500 kHz were measured in aim to search the weak-field dielectric response in PZT-PMnN-PSbN systems. A high value of εmax > 20000 was found at 1 kHz with the temperature Tm of around 575K. Using an extended Curie-Weis law the diffuse phase transition was determined. Fitting by using Vogel – Fulcher and power relationship indicated that the polarization fluctuation above the static freezing temperature behaves like as a spin-glass one. Cole – Cole analyses showed the non – Debye type relaxation in the system.

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Published

31-10-2012

How to Cite

[1]
T. T. Huy, N. D. T. Luan, T. V. Chuong, and L. V. Hong, “Dielectric and Relaxor Ferroelectric Properties in \(\text{PZT-PMnN-PSbN}\) Ceramics”, Comm. Phys., vol. 22, no. 3, p. 229, Oct. 2012.

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Vol. 22 No. 3 (2012)

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Papers

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Received 15-08-2012
Accepted 27-09-2012
Published 31-10-2012

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