Dielectric and Relaxor Ferroelectric Properties in \(\text{PZT-PMnN-PSbN}\) Ceramics

Than Trong Huy, Nguyen Dinh Tung Luan, Truong Van Chuong, Le Van Hong
Author affiliations

Authors

  • Than Trong Huy Hue University
  • Nguyen Dinh Tung Luan Industrial College of Hue
  • Truong Van Chuong Hue Science University
  • Le Van Hong Institute of Material Science

DOI:

https://doi.org/10.15625/0868-3166/22/3/2263

Keywords:

relaxor ferroelectric, PZT-PMnN-PSbN, Columbite precursor rout, diffuse phase transition, nanopolar regions

Abstract

The rhombohedral perovskite 0.9Pb(Zr0.5Ti0.5)O3 – xPb(Mn1/3Nb1/3)O3 – (0.1-x)Pb(Sb1/2Nb1/2)O3, x = 0.05; 0.06; 0.07; 0.08; 0.09; 0.1 (PZT – PMnN – PSbN) ceramic was synthesized by the Columbite precursor rout. The temperature dependence of dielectric constant and its loss in a frequency region of 0.1 kHz – 500 kHz were measured in aim to search the weak-field dielectric response in PZT-PMnN-PSbN systems. A high value of εmax > 20000 was found at 1 kHz with the temperature Tm of around 575K. Using an extended Curie-Weis law the diffuse phase transition was determined. Fitting by using Vogel – Fulcher and power relationship indicated that the polarization fluctuation above the static freezing temperature behaves like as a spin-glass one. Cole – Cole analyses showed the non – Debye type relaxation in the system.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

A. I. Kingon, S. K. Streiffier, C. Basceri and S. R. Summerfelt, Mat. Res. Bull. 21 (1996) 46. DOI: https://doi.org/10.1557/S0883769400035910

D. L. Polla and L. F. Francis, Mat. Res. Bull. 21 (1996) 59. DOI: https://doi.org/10.1557/S0883769400035934

S. Saha and T. P. Sinha, J. Phys.; Condens. Matter 14 (2002) 249. DOI: https://doi.org/10.1088/0953-8984/14/15/301

S. K. Sinha, R. N. P. Choudhary, S. N. Choudhary, T. P. Sinha, Materials Letters 51 (2001) 336. DOI: https://doi.org/10.1016/S0167-577X(01)00315-9

L. E. Cross, Ferroelectrics, 76, 241 (1987); (b) L. E. Cross, Ferroelectrics 151 (1994) 305

S. B. Majumdar, S. Bhattacharyya and R. S. Katiyar, J. Appl. Phys. 99 (2006) 024108. DOI: https://doi.org/10.1063/1.2158131

M. Maglion and M. Belkaoumi, Phys. Rev. B 45 (1992) 2029. DOI: https://doi.org/10.1103/PhysRevB.45.2029

G. Burns and F. H. Dacol, Solid State Commun. 48 (1983) 853. DOI: https://doi.org/10.1016/0038-1098(83)90132-1

J.Chen, H.M. Chan, M.P. Harmer, J.Am. Ceram, Soc., 72(4) (1989) 593. DOI: https://doi.org/10.1111/j.1151-2916.1989.tb06180.x

Y. Xu, Ferroelectric, Materials and Their Applications, North Holland (1991)

S.P. Singh, A.K. Singh, D. Pandey, J. Mater. Res. 18 (2003) 2677 DOI: https://doi.org/10.1557/JMR.2003.0155

S.B. Lee, K.H. Lee, H. Kim, Jpn. J. Appl. Phys. 41 (2002) 5266. DOI: https://doi.org/10.1143/JJAP.41.L1155

D.R. Chen, Y.Y. Guo, Electron. Element. Mater 1 (1982) 25.

Sinclair D C  West A R, J Appl Phys, 66 (1989) 38351. DOI: https://doi.org/10.1111/j.1751-0813.1989.tb09783.x

J.R. Macdonald, Impedance Spectroscopy Emphasizing Solid Materials and Systems, Wiley, New York, (1987).

K. S. Cole and R. H. Cole J. Chem. Phys. 9 (1941). 341 DOI: https://doi.org/10.1063/1.1750906

G. A. Smolensky, A. I. Agranovskaya, S. N. Popov and V. A. Isupov, Sov. Phys. Tech. Phys. 3 (1958) 1981.

N. Setter and L. E. Cross, J. Appl. Phys. 51 (1980) 4356. DOI: https://doi.org/10.1063/1.328296

C. A. Randall and A. S. Bhalla, Jpn. J. Appl. Phys. 29 (1990) 327. DOI: https://doi.org/10.1143/JJAP.29.327

X. He, X. Zeng, X. Zheng, P. Qiu, W. Cheng, A. Ding, Journal of Physics: Conference Series 152 (2009) 012068. DOI: https://doi.org/10.1088/1742-6596/152/1/012068

K. Bormanis, A. I. Burkhanova, A. V. Shil′nikova, A. Sternberg, S. A. Satarova, Journal of Optoelectronics and Advanced Materials Vol. 6(1) (2004) 341.

R. Pirc and R. Blinc, Physical review B 76 (2007) 020101. DOI: https://doi.org/10.1103/PhysRevB.76.020101

B. Mihailova, B.J. Maier, N. Waeselmann, C. Paulmann, M. Gospodinov, U. Bismayer (2011) 12th European Meeting on Ferroelectricity, 3A-2O

Downloads

Published

31-10-2012

How to Cite

[1]
T. T. Huy, N. D. T. Luan, T. V. Chuong and L. V. Hong, Dielectric and Relaxor Ferroelectric Properties in \(\text{PZT-PMnN-PSbN}\) Ceramics, Comm. Phys. 22 (2012) 229. DOI: https://doi.org/10.15625/0868-3166/22/3/2263.

Issue

Vol. 22 No. 3 (2012)

Section

Papers

License

Authors who publish with CIP agree with the following terms:
  1. The manuscript is not under consideration for publication elsewhere. When a manuscript is accepted for publication, the author agrees to automatic transfer of the copyright to the editorial office.
  2. The manuscript should not be published elsewhere in any language without the consent of the copyright holders. Authors have the right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal’s published version of their work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
  3. Authors are encouraged to post their work online (e.g., in institutional repositories or on their websites) prior to or during the submission process, as it can lead to productive exchanges or/and greater number of citation to the to-be-published work (See The Effect of Open Access).
Crossref
Scopus
Google Scholar
Europe PMC
Received 15-08-2012
Accepted 27-09-2012
Published 31-10-2012

Most read articles by the same author(s)