Study on adsorption of phosphate from aqueous solution by nanomaterial CeO2
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DOI:
https://doi.org/10.15625/2525-2321.2017-00498Keywords:
CeO2, gelatine, combustion method, phosphate (PO43-) adsorptionAbstract
The synthesis of nanosize single phase CeO2 by gelatine gel combustion method was investigated. The prepared material was characterized by X- ray diffraction, thermogravimetric and differential thermal analysis, scanning electron microscopy and transmission electron microscopy measurements. At optimum conditions, such as pH 3, the molar ratio of Ce4+/gelatine 1/1, and a calcination temperature of 550 oC for 2 hours, the material with average size < 30 nm was synthesized. From the results of phosphate adsorption, adsorption equilibrium time of the material was determined at 60 minutes. The phosphate adsorption process in aqueous solution followed the Langmuir isothermal model with Qmax= 152.66 mg/g.
Keywords. CeO2, gelatine, combustion method, phosphate (PO43-) adsorption.
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Phuong Thao, Do Quang Trung, Dang Thi Thu Huong, Cong Tien Dung. Research by lanthanum modifiedlaterite material treatment fluoride ion adsorption and phosphate in wastewater, Vietnam Journal of Chemistry, 54(3) 356-361(2016)
Recillas S., Colón J., Casals E., González E., Puntes V., Sánchez A., Font X. Chromium VI Adsorption on Cerium Oxide Nanoparticles and Morphology Changes during the Process. J. Hazard. Mater., 184 (1-3), 425-431 (2010).
Luu Minh Dai, Nguyen Gia Hung, Vo Quang Mai, Dao Ngoc Nhiem. Low temperature synthesisof nanostructured cerium dioxide by auto combustion process of polyvinyl alcohol-cerium nitrate gel. Vietnam Journal of Chemistry, 42(4), 444-448 (2004).
Luu Minh Dai, Dao Ngoc Nhiem, Nguyen Van Phu, Duong Thi Lim. Synthesis of nanostructured of CeO2-Al2O3 by combustion method, Vietnam Journal of Chemistry, 49(4), 405-408 (2011).
Dao Ngoc Nhiem,Luu Minh Dai, Nguyen Duc Van, Duong Thi Lim. Catalytic oxidation of carbon monoxide over nanostructured CeO2–Al2O3 prepared by combustion method using polyvinyl alcohol, J. Ceramics International, 39, 3381-3385 (2013).
Bui Van Thang, Le Ba Thuan. An investigation of phosphorus adsorption capacity by modified bentonite: effect of ph, concomitant anion and adsorption mechanism. Vietnam Journal of Chemistry, 51(3AB), 407-412 (2013).
Vietnam Organization for Standardization 5815:2001. NPK fertilizer-Test Method, (2008).
Hui Deng, Xili Yu. Adsorption of fluoride, arsenate and phosphate in aqueous solution by cerium impregnated fibrous protein, Chemical Engineering Journal, 184, 205-212 (2012).
Liu Chang - jiun, Li Yan-zhong et al. Adsorption removal of phosphate from aqueous solution by active red mud, Journal of Environmental Science, 19, 1166-1170 (2007).
Contreras A. R., García A., González E., Casals E., Puntes V., Sánchez A., Font, X. Recillas S. Potential Use of CeO2, TiO2 and Fe3O4 Nanoparticles for the Removal of Cadmium from Water, Desalin. Water Treat, 41(1-3), 296-300 (2012).
Recillas S., García A., González E., Casals E., Puntes V., Sánchez A., Font X. Use of CeO2, TiO2 and Fe3O4 Nanoparticles for the Removal of Lead from Water. Toxicity of Nanoparticles and Derived Compounds. Desalination, 277(1-3), 213-220 (2011).
Yin S., Minamidate Y., Tonouchi S., Goto T., Dong Q., Yamane, Sato T. Solution synthesis of homogeneous plate-like multifunctional CeO2 particles, RSC Advances, 2, 5976-5982 (2012).