Synthesis and electrochemical performance of MoO2/graphene nanomaterials as anode for lithium-ion battery
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DOI:
https://doi.org/10.15625/2525-2321.2017-00485Keywords:
Molybdenum dioxide, graphene composites, lithium-ion batteriesAbstract
In this articles, molybdenum dioxide/graphene composites were successfully prepared by a hydrothermal method. The results indicated graphene composition affects the properties of the electrochemical electrode, increased to 10 wt%, the molybdenum dioxide particles were uniformly deposited on the graphene sheets. The samples used as the electrode material for lithium batteries; it exhibited high reversible specific capacities of 1267 mAhg-1 at the second cycle and 629 mAhg-1 after 60 cycles. The outstanding electrochemical performance of the composite can be attributed to the synergistic interaction between molybdenum dioxide and graphene. There were enough void spaces to buffer volume change in the structure. Furthermore, graphene nanosheets in the hybrid material could act as not only lithium storage electrodes but also electronic conductive channels to improve the electrochemical performances.
Keywords. Molybdenum dioxide, graphene composites, lithium-ion batteries.
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References
Luo B., Liu S., Zhi L. Chemical approaches toward graphene-based nanomaterials and their applications in energy-related areas, Small, 8, 630-646 (2012).
Liu D., Cao G. Engineering nanostructured electrodes and fabrication of film electrodes for efficient lithium ion intercalation, Energy Environ. Sci., 3, 1218-1237 (2010).
Zhang W., Zeng Y., N. Xiao N. et al. One-step electrochemical preparation of graphene-based heterostructures for Li storage, J. Mater. Chem., 22, 8455-8461 (2012).
Xie D., Yuan W., Dong Z. et al. Facile synthesis of porous NiO hollow microspheres and its electrochemical lithium-storage performance, Electrochim. Acta, 92, 87-92 (2013).
Wang J., Yang N., Tang H. et al. Accurate Control of Multishelled Co3O4 Hollow Microspheres as High-Performance Anode Materials in Lithium-Ion Batteries, Angew. Chem., 125, 6545-6548 (2013).
Luo J., Liu J., Zeng Z. et al. Three-Dimensional Graphene Foam Supported Fe3O4 Lithium Battery Anodes with Long Cycle Life and High Rate Capability, Nano Lett., 13, 6136-6142 (2013).
Liu Y., Zhang H., Ouyang P. et al. One-pot hydrothermal synthesized MoO2 with high reversible capacity for anode application in lithium ion battery, Electrochim. Acta, 102, 429-435 (2013).
Gao F., Zhang L., Huang S. Fabrication horizontal aligned MoO2/single-walled carbon nanotube nanowires for electrochemical supercapacitor, Mater. Lett., 64, 537-540 (2015).
Cho W., Song J. H., Kim J. H. et al. Electrochemical characteristics of nano-sized MoO2/C composite anode materials for lithium-ion batteries, J. Appl. Electrochem., 42, 909-915 (2012).
Yao Y., Xu C., Yu S. et al. Facile Synthesis of Mn3O4–Reduced Graphene Oxide Hybrids for Catalytic Decomposition of Aqueous Organics, Ind. Eng. Chem. Res., 52, 3637-3645 (2013).
Wu Z S., Ren W., Wen L. et al. Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance, ACS Nano, 4, 3187-3194 (2010).
Seng K. H., Du G. D., Li L. et al. Facile synthesis of graphene–molybdenum dioxide and its lithium storage properties, J. Mater. Chem., 22, 16072-16077 (2014).
Singh V., Joung D., Zhai L. et al. Graphene based materials: past, present and future, Prog. in Mater. Sci., 56, 178-1271 (2011).
Ferrari A C., Meyer J C., Scardaci V. et al. Raman Spectrum of Graphene and Graphene Layers, Phys.
Rev. Lett., 97, 187401 (2006).
Tang Q., Shan Z., Wang L. et al. MoO2-graphene nanocomposite as anode material for lithium-ion batteries, Electrochim. Acta, 79, 148-153 (2012).
Shi Y., Guo B., Shi Q. et al. Ordered mesoporous metallic MoO2 materials with highly reversible lithium storage capacity, Nano Lett., 9, 4215-4220 (2009).
Sun Y., Hu X., Luo W., Huang Y. Ultrafine MoO2 nanoparticles embedded in a carbon matrix as a high-capacity and long-life anode for lithium-ion batteries, J. Mater. Chem. 22, 425-431 (2012).
Yang L C., Gao Q S., Zhang Y H. et al. Tremella-like molybdenum dioxide consisting of nanosheets as an anode material for lithium ion battery, Electrochem. Commun., 10, 118-122 (2008).
Xu Y., Yi R., Yuan B. High capacity MoO2/graphite oxide composite anode for lithium-ion batteries, J. Phys. Chem. Lett., 22, 309314-309320 (2012).
Tang Q., Shan Z., Wang L. et al. One-pot hydrothermal synthesized MoO2 with high reversible capacity for anode application in lithium ion battery, Electrochim. Acta, 102, 429-435 (2013).
Liu H., Du J. Synthesis and characterization of MoO2/P(St-co-MMA-co-AA) microspheres via microemulsion by γ-ray radiation, Solid State Sci., 8, 526-530 (2006).