Synthesis and structure of two platinum(II) complexes containing methyl eugenoxyacetate and 2-aminobenzothiazoles

Abstract

Two organometallic complexes of Pt(II), trans-[PtCl₂(Meteug)(Bzt)] (M1) and trans-[PtCl₂(Meteug)(6-MeOBzt)] (M2) (Meteug: methyl eugenoxyacetate, Bzt: 2-aminobenzothiazole, MeOBzt: 2-amino-6-methoxybenzothiazole), have been synthesized for the first time. The structures of M1 and M2 were determined by analysis of Pt and water of hydration proportion, IR, ¹H NMR and ¹³C NMR spectra. Meteug coordinates with Pt(II) through C=C of the allyl group in both compounds, Bzt and MeOBzt coordinate with Pt(II) via N heteroatom and at trans position compared to the allyl group.