Structures of 2,5-diaryl- and 2,3,5,6-tetra[3,2-b]thiophene synthesized by the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction
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DOI:
https://doi.org/10.15625/0866-7144.2016-00385Keywords:
thieno[3, 2-b]thiophene, palladium-catalyzed, Suzuki-Miyaura, cross-coupling.Abstract
The crystal structures of 2,5-di(ethoxyphenyl)-3,6-dibromothieno[3,2-b]thiophene (I) and 2,5-di(ethoxyphenyl)-3,6-diphenylthieno[3,2-b]thiophene (II) have been studied in order to evaluate the planarity of these molecules. The aromatic systems introduced to the thieno[3,2-b]thiophene core structure show a degree of rotation from 30.94° to 66.56°. The crystal packing of (I) are characterized by π×××π stacking, while in (II), C-H×××p and C-H×××O interactions are observed.Downloads
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Published
28-12-2016
How to Cite
Hien, N., Ngan, N. B., Dat, N. D., & Meervelt, L. van. (2016). Structures of 2,5-diaryl- and 2,3,5,6-tetra[3,2-b]thiophene synthesized by the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. Vietnam Journal of Chemistry, 54(6), 672. https://doi.org/10.15625/0866-7144.2016-00385
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