EFFECTS OF INTERFACIAL ADHESION ON DEFORMATION AND FRACTURE BEHAVIOUR OF COMPOSITES BASED ON POLYPROPYLENE AND GLASS BEADS

Authors

  • Nguyen Viet Dung Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovskeho nam. 2, CZ-162 06 Prague 6, Czech Republic

DOI:

https://doi.org/10.15625/2525-2518/54/1A/11841

Keywords:

polypropylene, glass bead, tensile mechanical, J-integral.

Abstract

In this study, the isotactic polypropylene, a semicrystalline polymer, was used as a matrix for composites containing 20% and 40% (by weight) of glass bead filler. Selected surface treatment was applied to obtain different adhesion between particles and polymer matrix. In addition to non-treated filler, filler treated with i) a release agent (labelled as NO adhesion) and ii) an adhesion promoter (labelled as GOOD adhesion) were incorporated into the matrix. The morphology, tensile mechanical and fracture behaviour (J-integral) were investigated. Morphology observation revealed a poor interfacial adhesion in the case of non-treated and “NO adhesion” samples represented with debonding of particles. In contrast, strong particle-matrix interactions were confirmed in “GOOD adhesion” samples. The presence of rigid filler particles increased the stiffness, while strain at break was decreased with the lowest value for the composites with strong interfacial adhesion. On the other hand, the higher rigidity and lower deformability decreased in fracture toughness.

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Published

2018-03-16

Issue

Section

Articles