Synthesis and Characterization of RbxMn[Fe(CN)]6 and Mn3[Cr(CN)6]2

Phung Kim Phu; Nguyen Minh Thuan; Tran Nam Trung; Nguyen Van Minh

doi:10.15625/0868-3166/21/1/87

Synthesis and Characterization of Rb_xMn[Fe(CN)]₆ and Mn₃[Cr(CN)₆]₂

Phung Kim Phu, Nguyen Minh Thuan, Tran Nam Trung, Nguyen Van Minh

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Authors

Phung Kim Phu
Nguyen Minh Thuan
Tran Nam Trung
Nguyen Van Minh

DOI:

https://doi.org/10.15625/0868-3166/21/1/87

Abstract

We present the synthesis and detailed characterization of Rb_xMn[Fe(CN)]₆ and Mn₃[Cr(CN)₆]₂ compounds. The composition of the materials significantly depends on the preparation conditions. Analysis of Raman spectroscopic results and X-ray powder diffraction data yielded a further assessment of the changes in structural features. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structure that appear to be associated with the synthesis method used.

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Published

31-03-2011

How to Cite

[1]

P. K. Phu, N. M. Thuan, T. N. Trung and N. V. Minh, Synthesis and Characterization of RbxMn[Fe(CN)]6 and Mn3[Cr(CN)6]2, Comm. Phys. 21 (2011) 19. DOI: https://doi.org/10.15625/0868-3166/21/1/87.

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Issue

Vol. 21 No. 1 (2011)

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Papers

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