Sensitive Organophosphorus and Carbamate Pesticides Biosensor Based on Acetylcholinesterase and CdZnSe/ZnS Ternary Alloy Quantum Dots

Nguyen Ngoc Hai, Nguyen Hai Yen, Duong Thi Giang, Nguyen Duc Nhat, Pham Thu Nga, Dao Tran Cao
Author affiliations

Authors

  • Nguyen Ngoc Hai Institute of Materials Science, Vietnamese Academy of Science and Technology, No.18, Hoang Quoc Viet Road, Cau Giay Dist., Hanoi City, Vietnam
  • Nguyen Hai Yen Institute of Materials Science, Vietnamese Academy of Science and Technology
  • Duong Thi Giang Institute of Materials Science, Vietnamese Academy of Science and Technology
  • Nguyen Duc Nhat Institute of Materials Science, Vietnamese Academy of Science and Technology
  • Pham Thu Nga Institute of Materials Science, Vietnamese Academy of Science and Technology
  • Dao Tran Cao Institute of Materials Science, Vietnamese Academy of Science and Technology

DOI:

https://doi.org/10.15625/0868-3166/24/3/3791

Keywords:

pesticide, biosensors, ternary alloy quantum dots, photoluminescence

Abstract

This report presents the results of ternary alloy quantum dots (TQDs) manufacturing and its superior optical properties to fabricate the biosensor for pesticide detection. The explanation for the changes in PL intensity based on the change of electronic charges that alters the pH value of the surrounding environment, and the types of interaction on the surface of CdZnSe/ZnS TQDs were discussed. We show the decomposition process of the indicator (ATCh) with the catalysis from acetylcholinesterase enzyme (AChE) that inhibited by organophosphorus and carbamate pesticides including Trichlorfon (TF), Cypermethrin (CH), Abamectin (AT), and Carbosulfan (CS) with concentrations from 0.05 ppm to 10 ppm.

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References

Z. Deng, H.Yan, and Y. Liu, J. Am. Chem. Soc. 131 (2009) 17744–17745. DOI: https://doi.org/10.1021/ja908408m

Chen Y., Vela J et al, Journal of the American Chemical Society. 130 (2008) 5026-5027. DOI: https://doi.org/10.1021/ja711379k

Q.Chen, Y. Fung, Electrophoresis. 31 (2010) 3107-3114. DOI: https://doi.org/10.1002/elps.201000260

Z. Zheng, Zhou Y., Li X., Liu S., and Tang Z, Biosensors and Bioelectronics. 26 (2011) 3081–3085. DOI: https://doi.org/10.1016/j.bios.2010.12.021

T.T.K.Chi et al,, Adv. Nat. Sci.: Nanosci.Nanotechnol. 3 (2012) 035008. DOI: https://doi.org/10.1088/2043-6262/3/3/035008

P.T. Nga, V.D. Chinh, V.T.H. Hanh, N.X. Nghia and P.T. Dzung, Int. J. Nanotechnol. 8 (2011) 347-359. DOI: https://doi.org/10.1504/IJNT.2011.038211

Mahler B., Spinicelli P., Buil S., Quelin X., Hermier J. P., Dubertret B, Nat Mater 7 (2008) 659-664. DOI: https://doi.org/10.1038/nmat2222

N.N. Hai, V.D. Chinh , T.K. Chi , U.T.D. Thuy , N.X. Nghia, D.T. Cao, P.T. Nga, Key Engineering Materials. 495 (2012) 314-318. DOI: https://doi.org/10.4028/www.scientific.net/KEM.495.314

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Published

21-08-2014

How to Cite

[1]
N. N. Hai, N. H. Yen, D. T. Giang, N. D. Nhat, P. T. Nga and D. T. Cao, Sensitive Organophosphorus and Carbamate Pesticides Biosensor Based on Acetylcholinesterase and CdZnSe/ZnS Ternary Alloy Quantum Dots, Comm. Phys. 24 (2014) 225. DOI: https://doi.org/10.15625/0868-3166/24/3/3791.

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Papers
Received 20-03-2014
Published 21-08-2014