Correlation between sintering temperature and dwell time on structural and ferroelectric properties of NiTiO\(_3\)-CoFe\(_2\)O\(_4\) ceramics

Luong Huu Bac, Dang Duc Dung, Nguyen Hoang Tuan, Nguyen Hoang Thoan, Pham Van Thang
Author affiliations

Authors

DOI:

https://doi.org/10.15625/0868-3166/18800

Keywords:

NiTiO3-CoFe2O4, ferromagnetism, composite, sintering

Abstract

The 0.9NiTiO3-0.1CoFe2O4 ceramic was prepared by sol-gel method. The structural and ferroelectric properties of the ceramic were investigated. Structure of the materials was analyzed by X-ray diffraction and scanning electron microscopy. Fabricated materials consists of NiTiO3 with rhombohedral phase structure and CoFe2O4 with cubic structure. The effect of sintering temperature and dwell time on the phase, microsctructure and ferroelectric properties of the ceramics was investigated. As the sintering temperature and dwell time increased, the density of the bulk sample was improved. The material sample was sintered at 1200oC for 10 h with large particle size (~6 µm), few pores and high density ~97.5%. The composite material displayed ferroelectric properties, as evidence from the characteristic hysteresis loop observed in ferroelectric materials. At sintering temperatures of 1000°C and 1100°C for 2 and 5 h,  the sample exhibited poor ferroelectric characteristics. However, when the sample was sintered at 1200°C for 10 h, a notable enhancement in ferroelectric properties was observed.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

M.M. Vopson, Fundamentals of Multiferroic Materials and Their Possible Applications, Crit. Rev. Solid State Mater. Sci. 40 (2015) 223–250. DOI: https://doi.org/10.1080/10408436.2014.992584

P.A. Jha, A.K. Jha, Effect of sintering temperature on the grain growth and electrical properties of barium zirconate titanate ferroelectric ceramics, J. Mater. Sci. Mater. Electron. 24 (2013) 1511–1518. DOI: https://doi.org/10.1007/s10854-012-0963-7

M.A. Ruiz-Preciado, A. Kassiba, A. Gibaud, A. Morales-Acevedo, Comparison of nickel titanate (NiTiO3) powders synthesized by sol-gel and solid state reaction, Mater. Sci. Semicond. Process. 37 (2015) 171–178. DOI: https://doi.org/10.1016/j.mssp.2015.02.063

G.S. Heller, J.J. Stickler, S. Kern, A. Wold, Antiferromagnetism in NiTiO3, J. Appl. Phys. 34 (1963) 1033. DOI: https://doi.org/10.1063/1.1729357

P. Van Thang, D.D. Dung, L.H. Bac, P.P. Hung, T.V.D. Ngoc, Structural, Optical, Ferroelectric and Magnetic Properties of NiTiO3 Ceramic Synthesized by Citrate Gel Method, Int. J. Nanosci. 20 (2021) 1–7. DOI: https://doi.org/10.1142/S0219581X21500046

T. Acharya, R.N.P. Choudhary, Structural, Ferroelectric, and Electrical Properties of NiTiO3 Ceramic, J. Electron. Mater. 44 (2015) 271–280. DOI: https://doi.org/10.1007/s11664-014-3426-5

R. Tursun, Y. Su, Q. Yu, J. Tan, Room-temperature coexistence of electric and magnetic orders in NiTiO3 and e ff ect of ethylene glycol, Mater. Sci. Eng. B. 228 (2018) 96–102. DOI: https://doi.org/10.1016/j.mseb.2017.11.009

P.P. Hung, D.D. Dung, N.H. Tuan, N.N. Trung, L.H. Bac, Iron induced room temperature ferromagnetism in ilmenite NiTiO3 materials, Mater. Lett. 209 (2017) 284–286. DOI: https://doi.org/10.1016/j.matlet.2017.08.026

M. Atif, M. Nadeem, W. Khalid, Z. Ali, Structural, magnetic and impedance spectroscopy analysis of (0.7)CoFe2O4+(0.3)BaTiO3 magnetoelectric composite, Mater. Res. Bull. 107 (2018) 171–179. DOI: https://doi.org/10.1016/j.materresbull.2018.07.026

R. Grigalaitis, M.M. Vijatović Petrović, J.D. Bobić, A. Dzunuzovic, R. Sobiestianskas, A. Brilingas, B.D. Stojanović, J. Banys, Dielectric and magnetic properties of BaTiO3 -NiFe2O4 multiferroic composites, Ceram. Int. 40 (2014) 6165–6170. DOI: https://doi.org/10.1016/j.ceramint.2013.11.069

K.P. Remya, R. Rajalakshmi, N. Ponpandian, Development of BiFeO3/MnFe2O4ferrite nanocomposites with enhanced magnetic and electrical properties, Nanoscale Adv. 2 (2020) 2968–2976. DOI: https://doi.org/10.1039/D0NA00255K

A. Jain, Y.G. Wang, N. Wang, Y. Li, F.L. Wang, Tuning the dielectric, ferroelectric and electromechanical properties of Ba0.83Ca0.10Sr0.07TiO3–MnFe2O4 multiferroic composites, Ceram. Int. 46 (2020) 7576–7585. DOI: https://doi.org/10.1016/j.ceramint.2019.11.257

R.L. Coble, Sintering crystalline solids. I. intermediate and final state diffusion models, J. Appl. Phys. 32 (1961) 787–792. DOI: https://doi.org/10.1063/1.1736107

L.F. Zhu, B.P. Zhang, J.Q. Duan, B.W. Xun, N. Wang, Y.C. Tang, G.L. Zhao, Enhanced piezoelectric and ferroelectric properties of BiFeO3-BaTiO3 lead-free ceramics by optimizing the sintering temperature and dwell time, J. Eur. Ceram. Soc. 38 (2018) 3463–3471. DOI: https://doi.org/10.1016/j.jeurceramsoc.2018.03.044

L. Liu, H. Fan, S. Ke, X. Chen, Effect of sintering temperature on the structure and properties of cerium-doped 0.94(Bi0.5Na0.5)TiO3-0.06BaTiO3 piezoelectric ceramics, J. Alloys Compd. 458 (2008) 504–508. DOI: https://doi.org/10.1016/j.jallcom.2007.04.037

C. Jiten, R. Gaur, R. Laishram, K.C. Singh, Effect of sintering temperature on the microstructural, dielectric, ferroelectric and piezoelectric properties of (Na0.5K0.5)NbO3 ceramics prepared from nanoscale powders, Ceram. Int. 42 (2016) 14135–14140. DOI: https://doi.org/10.1016/j.ceramint.2016.06.029

E. Chandrakala, J. Paul Praveen, B.K. Hazra, D. Das, Effect of sintering temperature on structural, dielectric, piezoelectric and ferroelectric properties of sol-gel derived BZT-BCT ceramics, Ceram. Int. 42 (2016) 4964–4977. DOI: https://doi.org/10.1016/j.ceramint.2015.12.009

Y.H. Kwon, G.H. Lee, J.H. Koh, Effects of sintering temperature on the piezoelectric properties of (Bi,Na)TiO3-based composites for energy harvesting applications, Ceram. Int. 41 (2015) S792–S797. DOI: https://doi.org/10.1016/j.ceramint.2015.03.181

W. Cai, C. Fu, J. Gao, H. Chen, Effects of grain size on domain structure and ferroelectric properties of barium zirconate titanate ceramics, J. Alloys Compd. 480 (2009) 870–873. DOI: https://doi.org/10.1016/j.jallcom.2009.02.049

M.S. Alkathy, A. Hezam, K.S.D. Manoja, J. Wang, C. Cheng, K. Byrappa, K.C.J. Raju, Effect of sintering temperature on structural, electrical, and ferroelectric properties of lanthanum and sodium co-substituted barium titanate ceramics, J. Alloys Compd. 762 (2018) 49–61. DOI: https://doi.org/10.1016/j.jallcom.2018.05.138

H. CHENG, W. ZHOU, H. DU, F. LUO, D. ZHU, Effects of dwell time during sintering on electrical properties of 0.98(K0.5Na0.5)NbO3–0.02LaFeO3 ceramics, Trans. Nonferrous Met. Soc. China. 23 (2013) 2984–2988. DOI: https://doi.org/10.1016/S1003-6326(13)62824-1

Y. Li, Y. Guo, Q. Zheng, K.H. Lam, W. Zhou, Y. Wan, D. Lin, Enhancement in multiferroic and piezoelectric properties of BiFeO3-BaTiO3-Bi0.5Na0.5TiO3 lead-free ceramics with MnO2 addition by optimizing sintering temperature and

Downloads

Published

13-01-2024

How to Cite

[1]
L. H. Bac, D. D. Dung, N. H. Tuan, N. H. Thoan, and P. V. Thang, “Correlation between sintering temperature and dwell time on structural and ferroelectric properties of NiTiO\(_3\)-CoFe\(_2\)O\(_4\) ceramics”, Comm. Phys., vol. 34, no. 1, p. 63, Jan. 2024.

Issue

Section

Papers
Received 02-09-2023
Accepted 30-11-2023
Published 13-01-2024

Most read articles by the same author(s)