Evaluation of the hydrophobic and barrier properties of the polyurethane coatings covered by stearic acid thin layer

Anh Son Nguyen, Thuy Duong Nguyen, Thu Thuy Pham, Ke Oanh Vu, Thi Xuan Hang To, Lan Phuong Trinh, Xuan Thang Dam, Minh Quy Bui
Author affiliations

Authors

  • Anh Son Nguyen Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • Thuy Duong Nguyen Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • Thu Thuy Pham Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • Ke Oanh Vu Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • Thi Xuan Hang To Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • Lan Phuong Trinh Department of Chemical Technology, Hanoi University of Industry, Hanoi, Vietnam https://orcid.org/0009-0000-8722-9446
  • Xuan Thang Dam Department of Chemical Technology, Hanoi University of Industry, Hanoi, Vietnam
  • Minh Quy Bui Faculty of Chemistry, Thai Nguyen University of Sciences, Thai Nguyen, Vietnam https://orcid.org/0000-0002-6378-4899

DOI:

https://doi.org/10.15625/0868-3166/18506

Abstract

In this paper, a thin stearic acid (SA) film was deposited onto the polyurethane (PU) coatings with different concentrations of stearic acid in the ethanol (1 wt.%, 2 wt.% and 3 wt.%) by centrifuged technique. Fourier transform infrared spectra (FTIR) and water contact angle (WCA) method were performed to characterize and evaluate the hydrophobic layer formed on the surface of the samples. Then, the barrier property of the PU/SA was assessed by using electrochemical impedance spectroscopy (EIS) and accelerated salt spray test method. The results show that the presence of the stearic acid layer was effective for both hydrophobic and barrier properties, especially the samples prepared with 3 wt.% stearic acid. This work landmarks the need for improving the protection ability of polyurethane coatings for a metallic substrate.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

Q. A. Jawad, D. S. Zinad, R. D. Salim, A. A Al-Amiery, T. S. Gaaz, M. S. Takriff and A. A. H. Kadhum, Synthesis, Characterization, and Corrosion Inhibition Potential of Novel Thiosemicarbazone on Mild Steel in Sulfuric Acid Environment, Coatings 9 (11) (2019) 729. DOI: https://doi.org/10.3390/coatings9110729

J. Alcantara, D. Fuente, B. Chico, J. Simancas, I. Diaz and M. Morcillo, Marine Atmospheric Corrosion of Carbon Steel: A Review, Materials (Basel) 10 (3) (2017) 406. DOI: https://doi.org/10.3390/ma10040406

T. D. Nguyen, A. S. Nguyen, B. A. Tran, K. O. Vu, D. L. Tran, T. T. Phan, N. Scharnagl, M. L. Zheludkevich and T. X. H. To, Molybdate intercalated hydrotalcite/graphene oxide composite as corrosion inhibitor for carbon steel, Surf. Coat. Technol. 399 (2020) 126165. DOI: https://doi.org/10.1016/j.surfcoat.2020.126165

C. Wang, W. Gao, N. Liu, Y. Xin, X. Liu, X. Wang, Y. Tian, X. Chen and B. Hou, Covalent Organic Framework Decorated TiO2 Nanotube Arrays for Photoelectrochemical Cathodic Protection of Steel, Corros. Sci. 176 (2020) 108920. DOI: https://doi.org/10.1016/j.corsci.2020.108920

T. A. Truc, T. T. Thuy, V. K. Oanh, T. T. X. Hang, A. S. Nguyen, N. Caussé and N. Pébère, 8-hydroxyquinoline-modified clay incorporated in an epoxy coating for the corrosion protection of carbon steel, Surf. Interfaces 14 (2019) 26. DOI: https://doi.org/10.1016/j.surfin.2018.10.007

T. T. X. Hang, N. T. Dung, T. A. Truc, N. T. Duong, B. V. Truoc, P. G. Vu, T. Hoang, D. T. M. Thanh, M. -G. Olivier, Effect of silane modified nano ZnO on UV degradation of polyurethane coatings, Prog. Org. Coat. 79 (2015) 68. DOI: https://doi.org/10.1016/j.porgcoat.2014.11.008

P. Haghdadeh, M. Ghaffari, B. Ramezanzadeh, G. Bahlakeh and M. R. Saeb, Polyurethane coatings reinforced with 3-(triethoxysilyl)propyl isocyanate functionalized graphene oxide nanosheets: Mechanical and anti-corrosion properties, Prog. Org. Coat. 136 (2019) 105243. DOI: https://doi.org/10.1016/j.porgcoat.2019.105243

I. C. P. Margarit-Mattos, EIS and organic coatings performance: Revisiting some key points, Electrochim. Acta, 354 (2020) 136725. DOI: https://doi.org/10.1016/j.electacta.2020.136725

G. Cai, S. Xiao, C. Deng, D. Jiang, X. Zhang and Z. Dong, CeO2 grafted carbon nanotube via polydopamine wrapping to enhance corrosion barrier of polyurethane coating, Corros. Sci. 178 (2021) 109014. DOI: https://doi.org/10.1016/j.corsci.2020.109014

S. Li, S. Wang, X. Du, H. Wang, X. Cheng and Z. Du, Waterborne polyurethane coating based on tannic acid functionalized Ce-MMT nanocomposites for the corrosion protection of carbon steel, Prog. Org. Coat. 163 (2022) 106613. DOI: https://doi.org/10.1016/j.porgcoat.2021.106613

R. Abakah, F. Huang, Q. Hu, Y. Wang and J. Liu, Comparative Study of Corrosion Properties of Different Graphene Nanoplate/Epoxy Composite Coatings for Enhanced Surface Barrier Protection, Coatings 11 (3) (2021) 285. DOI: https://doi.org/10.3390/coatings11030285

X. Xiao, Z. Ye, G. Meng and L. Gu, Mussel-inspired preparation of superhydrophobic mica nanosheets for long-term anticorrosion and self-healing performance of epoxy coatings, Prog. Org. Coat. 178 (2023) 107456. DOI: https://doi.org/10.1016/j.porgcoat.2023.107456

Y. Ye, D. Yang, D. Zhang, H. Chen, H. Zhao, X. Li and L. Wang, POSS-tetraaniline modified graphene for active corrosion protection of epoxy-based organic coating, Chem. Eng. J 383 (2020) 123160. DOI: https://doi.org/10.1016/j.cej.2019.123160

W. Zhang, Y. Chen, M. Chen, S. Zhao, J. Mao, A. Qu, W. Li, Y. Zhao, N. Huang and G. Wan, Strengthened corrosion control of poly (lactic acid) (PLA) and poly (ε-caprolactone) (PCL) polymer-coated magnesium by imbedded hydrophobic stearic acid (SA) thin layer, Corros. Sci. 112 (2016) 327. DOI: https://doi.org/10.1016/j.corsci.2016.07.027

M. O. Penna, A. A. Silva, F. F. do Rosário, S. De Souza Camargo and B. G. Soares, Organophilic nano-alumina for superhydrophobic epoxy coatings, Mater. Chem. Phys. 255 (2020) 123543. DOI: https://doi.org/10.1016/j.matchemphys.2020.123543

O. R. Pardini and J. I. Amalvy, FTIR, 1H-NMR spectra, and thermal characterization of water-based polyurethane/acrylic hybrids, J. Appl. Polym. Sci., 107 (2) (2008) 1207. DOI: https://doi.org/10.1002/app.27188

Downloads

Published

15-12-2023

How to Cite

[1]
A. S. Nguyen, “Evaluation of the hydrophobic and barrier properties of the polyurethane coatings covered by stearic acid thin layer”, Comm. Phys., vol. 33, no. 4, p. 447, Dec. 2023.

Issue

Vol. 33 No. 4 (2023)

Section

Papers

License

Authors who publish with CIP agree with the following terms:
  1. The manuscript is not under consideration for publication elsewhere. When a manuscript is accepted for publication, the author agrees to automatic transfer of the copyright to the editorial office.
  2. The manuscript should not be published elsewhere in any language without the consent of the copyright holders. Authors have the right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal’s published version of their work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
  3. Authors are encouraged to post their work online (e.g., in institutional repositories or on their websites) prior to or during the submission process, as it can lead to productive exchanges or/and greater number of citation to the to-be-published work (See The Effect of Open Access).
Crossref
Scopus
Google Scholar
Europe PMC
Received 12-07-2023
Accepted 19-09-2023
Published 15-12-2023

Most read articles by the same author(s)