Structure and Optical Property of Gold Nanoparticles Synthesized by Modified Polyol Method
Author affiliations
DOI:
https://doi.org/10.15625/0868-3166/2021/15933Keywords:
polyol method, NaBH4, PVP, Au nanoparticlesAbstract
In this research, Au nanoparticles were successfully synthesized by modified polyol method with commercial precursors to be gold (III) chloride trihydrate (HAuCl4·3H2O), ethylene glycol (EG), poly(vinylpyrrolidone) (PVP), sodium borohydride (NaBH4). The structure and properties of as-prepared Au nanoparticles have been investigated by X ray diffraction (XRD), transmission electron microscopy (TEM), and UV-vis-NIR spectroscopy. As a result, Au nanoparticles with the average particle size of 28.80 nm were successfully synthesized in the range of about 50 nm. It is evidenced that the assembly of gold nanoparticles was presented in their nucleation, growth, and formation.
Downloads
Metrics
References
Burda C., Chen X., Narayanan R., and El-Sayed M.A, Chemistry and Properties of Nanocrystals of Different Shapes, Chem. Rev. 105 (2005) 1025-1102.
Xu Z., Yong J.K.C, New Developments in Gold Nanomaterials Research, Series: Nanotechnology Science and Technology, Nova Science Publishers, Inc. Long N.V., Yong Y., Lin Z.L., Cao Y., Thi C.M., and Nogami M. - Controlled Synthesis of Gold Nanoparticles by Modified Polyol Methods for Plasmonic Applications, Chapter 2, 25-37 (2016).
Xu Z., Yong J.K.C, New Developments in Gold Nanomaterials Research, Series: Nanotechnology Science and Technology, Nova Science Publishers, Inc. Long N.V., Yong Y., Lin Z.L., Cao Y., Thi C.M., and Nogami M. - New Developments of Gold Nanoparticles in Plasmonic Sensing, Chapter 7, 115-146 (2016).
Fiévet F., Ammar-Merah S., Brayner R., Chau F., Giraud M., Mammeri F., Peron J., Piquemal J-Y., Sicard L., Viau G., The polyol process: a unique method for easy access to metal nanoparticles with tailored sizes, shapes and compositions, Chem. Soc. Rev. 47(14) (2018) 5187-5233.
Ammar S., Fiévet F., Polyol Synthesis: A Versatile Wet-Chemistry Route for the Design and Production of Functional Inorganic Nanoparticlesl, Nanomater. 10(6) (2020) 1217.
Rodrigues T.S., Zhao M., Yang T.H., Gilroy K.D., da Silva A.G., Camargo P.H., and Xia Y., Synthesis of colloidal metal nanocrystals: A comprehensive review on the reductants, Chem. Eur. J. 24(64) (2018) 16944-16963.
Yue H., Zhao Y., Ma X., Gong J, Ethylene glycol: properties, synthesis, and applications, Chem. Soc. Rev. 41(11) (2012) 4218-4244.
Long N.V., Ohtaki M., Yuasa M., Yoshida S., Kuragaki T., Thi C.M., and Nogami M., Research Article Synthesis and Self-Assembly of Gold Nanoparticles by Chemically Modified Polyol Methods under Experimental Control, J. Nanomater. 2013, ID 793125, 8 pages, Hindawi Publishing Corporation (2013).
Long N.V., Yang Y., Thi C.M., Phuc L.H., Lu L.T., and Nogami M., Controlled Synthesis and Ferrimagnetism of Homogeneous Hierarchical CoFe2O4 Particles, J. Electron. Mater. 46 (2017) 6001-6008.
Long N.V., Yang Y., Thi C.M., Phuc L.H., and Nogami M, Polyol-Mediated Synthesis, Microstructure and Magnetic Properties of Hierarchical Sphere, Rod, and Polyhedral α-Fe2O3 Oxide Particles, J. Electro. Mater., 46 (6) (2017) 3615-3621.
Long N.V., Yang Y., Thi C.M., Phuc L.H., and Nogami M, Controlled Synthesis and Magnetic Properties of Uniform Hierarchical Polyhedral α-Fe2O3 Particles, J. Electron. Mater., 46 (6) (2017) 3301-3308.
Long N.V., Yang Y., Phuc L.H., Kien P.T., Nogami M., Synthesis, Structure, and Property of Uniform Gold Nanoparticles by Modified Polyol Method, 12th AUN/SEED-net RCME & ISMSE 2019, HCMC, Vietnam, October 10-11, 66-72 (2019).
Do H.T., Duong V.T.T., Nghia N.T., Tran N.H., Nghiem L.T.H, Seeded growth synthesis of gold nanorods for photothermal application, VJST, 56 (2) (2018) 148-157.
Diem P.H.N., Hoa T.T., Binh T.T, Synthesis and catalytic activity of branch gold nanoparticles in aqueous medium, VJST, 55 (5B) (2017) 227-235.
Oliveira P.F.D., Michalchuk A.A., Marquardt J., Feiler T., Prinz C., Torresi R.M., Camargo P.H.C., Emmerling F., Investigating the role of reducing agents on mechanosynthesis of Au nanoparticles, CrystEngComm., 22(38) (2020) 6261-6267.
Sierra-Martin B., and Fernandez-Barbero A., Particles and nanovoids for plasmonics, Adv. Colloid Interf. Sci. (2021) 102394.
Kelly K.L., Coronado E., Zhao L.L., Schatz G.C., The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment, J. Phys. Chem. B 107 (2003) 668-677.
Long N.V., Thi C.M., Nogami M., The Recent Patents and Highlights of Functionally Engineered Nanoparticles for Potential Applications in Biology, Medicine, and Nanomedicine, Curr. Phys. Chem. 4 (2014) 173-194.
Downloads
Published
How to Cite
Issue
Section
License
Authors who publish with CIP agree with the following terms:- The manuscript is not under consideration for publication elsewhere. When a manuscript is accepted for publication, the author agrees to automatic transfer of the copyright to the editorial office.
- The manuscript should not be published elsewhere in any language without the consent of the copyright holders. Authors have the right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal’s published version of their work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are encouraged to post their work online (e.g., in institutional repositories or on their websites) prior to or during the submission process, as it can lead to productive exchanges or/and greater number of citation to the to-be-published work (See The Effect of Open Access).
Accepted 23-05-2021
Published 04-07-2021
