Nghiên cứu tổng hợp và cấu trúc của hai phức chất K[PtCl3(isopropyl eugenoxyaxetat)] và [PtCl(isopropyl eugenoxyaxetat-1H)]2

Phạm Văn Thống, Nguyễn Thị Thanh Chi
Author affiliations

Authors

  • Phạm Văn Thống
  • Nguyễn Thị Thanh Chi

DOI:

https://doi.org/10.15625/4914

Keywords:

Isopropyl eugenoxyacetate, platinum(II) complex, NMR

Abstract

Two organometalliccomplexes of platinum(II) K[PtCl3(iso-Preug)] (M1) and [PtCl(iso-Preug-1H)]2 (M2) have been synthesized for the first time. The structures of M1 and M2 were determined by means of platinum analysis, IR, 1H, 13C NMR spectroscopy and X-ray diffraction. In complex M1, isopropyleugenoxyacetate (iso-Preug) only coordinates with platinum(II) at ethylenic double bond of allyl group. In M2, deprotonated iso-Preug is bound up with platinum(II) both at ethylenic double bond of allyl group and at C atom of benzene ring to generate dinuclear metallacyclic complex.

Keywords: Isopropyl eugenoxyacetate, platinum(II) complex, NMR.

Downloads

Download data is not yet available.

Published

10-09-2014

How to Cite

Thống, P. V., & Thanh Chi, N. T. (2014). Nghiên cứu tổng hợp và cấu trúc của hai phức chất K[PtCl3(isopropyl eugenoxyaxetat)] và [PtCl(isopropyl eugenoxyaxetat-1H)]2. Vietnam Journal of Chemistry, 52(3), 381. https://doi.org/10.15625/4914

Issue

Section

Articles