Nghiên cứu tương tác của muối Zeise với axit eugenoxyaxetic trong ancol.

Abstract

An esterification in the coordination sphere of platinum(II) is reported for the fist time. The reaction of Zeise's salt and eugenoxyacetic acid in an alcohol leads to formation of complexes containing either eugenoxyacetic acid or alkyl eugenoxyacetate. The structure of formed complexes were confirmed by elemental analysis, IR, MS and NMR spectroscopy. It is shown that h²-coordinated buthyl eugenoxyacetate was deprotonated to form a Pt-C(aryl) bond.