Preparation and characterizations of plasticized PMMA/PVC/Mg(ClO4)2 electrolytes

Do Quang Tham, Tran Thi Mai, Thai Hoang, Nguyen Thi Kim Dung, Nguyen Quang Tung, Nguyen Thi Dieu Linh, Lai Thi Huyen, Dam Xuan Thang, Do Van Cong, Mai Duc Huynh, Nguyen Thi Thai
Author affiliations

Authors

  • Do Quang Tham Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam https://orcid.org/0000-0001-5480-4360
  • Tran Thi Mai Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Thai Hoang Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nguyen Thi Kim Dung National Academy of Education Management, 31 Phan Dinh Giot, Thanh Xuan, Ha Noi, Viet Nam
  • Nguyen Quang Tung Faculty of Chemical Technology, HaUI, Tay Tuu, North Tu Liem, Ha Noi, Viet Nam
  • Nguyen Thi Dieu Linh Faculty of Chemical Technology, HaUI, Tay Tuu, North Tu Liem, Ha Noi, Viet Nam
  • Lai Thi Huyen Faculty of Chemical Technology, HaUI, Tay Tuu, North Tu Liem, Ha Noi, Viet Nam
  • Dam Xuan Thang Faculty of Chemical Technology, HaUI, Tay Tuu, North Tu Liem, Ha Noi, Viet Nam
  • Do Van Cong Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Mai Duc Huynh Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam
  • Nguyen Thi Thai Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Ha Noi, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/57/5/13661

Keywords:

polymer electrolytes, PMMA, PVC, magnesium perchlorate, ionic conductivity

Abstract

Electrolyte films based on poly(methyl methacrylate) (PMMA), poly(vinyl chloride) (PVC) were prepared by using casting method with the addition 100 wt.% to 240 wt.% of dioctyl phthalate (DOP), propylene carbonate (PC) as plasticizers and Mg(ClO4)2 as an electrolytic salt. The Fourier infrared spectra (FTIR), tensile, electrical properties, surface morphology of electrolyte films were investigated. The FTIR spectra of plasticized PMMA/PVC blends indicated that there were secondary interactions between plasticizers and PMMA/PVC matrix. There were also molecular interactions between Mg(ClO4)2 and the blends, which indicated that Mg(ClO4)2 was well dissolved and solvated in the blends. Tensile results showed that Mg(ClO4)2 improved the elongation at break and the reduced tensile strength and Young’s modulus of the blends due to this salt can act as an internal lubricant for the blends. The SEM and EDX-mapping micrographs showed the wrinkled surface morphology of the electrolyte film, all raw materials were dispersed regularly into each others at molecular and ionic levels. For the electrolytes containing 10 wt.% of Mg(ClO4)2, the ionic conductivity increased with increasing plasticizer content and achieved in the range of 1.80 × 10-4 - 1.03 × 10-3 (S/cm). For the electrolyte containing 200 wt.% of the plasticizer, the ionic conductivity increased with increasing magnesium salt content and achieved in the range of 2.31 × 10-4 - 4.57 × 10-3 (S/cm). 

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Published

08-10-2019

How to Cite

[1]
D. Q. Tham, “Preparation and characterizations of plasticized PMMA/PVC/Mg(ClO<sub>4</sub>)<sub>2</sub> electrolytes”, Vietnam J. Sci. Technol., vol. 57, no. 5, pp. 559–571, Oct. 2019.

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Materials

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