Copper triflate catalyzed Baeyer- Villiger oxidation of ketones

Dau Xuan Duc, Nguyen Thi Nguyet
Author affiliations

Authors

  • Dau Xuan Duc School of Chemistry, Vinh University, 182 Le Duan, Vinh City, Nghe An, Viet Nam
  • Nguyen Thi Nguyet School of Chemistry, Vinh University, 182 Le Duan, Vinh City, Nghe An, Viet Nam

DOI:

https://doi.org/10.15625/2525-2518/57/1/12589

Keywords:

oxidation, ketone, lactone, ester, catalyst

Abstract

A simple, efficient and eco-friendly method for Baeyer-Villiger oxidation reaction has been developed. The reaction employed m-CPBA as the oxidant with Cu(OTf)2 catalyst and was carried out in CH2Cl2 at room temperature. Nine lactones and ester were obtained in excellent yield (85-94%). Furthermore, the catalyst could be reused twice without considerable loss in activity.

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Published

18-02-2019

How to Cite

[1]
D. X. Duc and N. T. Nguyet, “Copper triflate catalyzed Baeyer- Villiger oxidation of ketones”, Vietnam J. Sci. Technol., vol. 57, no. 1, pp. 76–81, Feb. 2019.

Issue

Section

Environment