COPPER TRIFLATE CATALYZED BAEYER- VILLIGER OXIDATION OF KETONES

Dau Xuan Duc, Nguyen Thi Nguyet

Abstract


A simple, efficient and eco-friendly method for Baeyer-Villiger oxidation reaction has been developed. The reaction employed m-CPBA as the oxidant with Cu(OTf)2 catalyst and was carried out in CH2Cl2 at room temperature. Nine lactones and ester were obtained in excellent yield (85-94%). Furthermore, the catalyst could be reused twice without considerable loss in activity.

Keywords


oxidation, ketone, lactone, ester, catalyst

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DOI: https://doi.org/10.15625/2525-2518/57/1/12589

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Published by Vietnam Academy of Science and Technology