A study on the variation of zeta potential with mineral composition of rocks and types of electrolyte

Luong Duy Thanh; Rudolf Sprik

doi:10.15625/0866-7187/40/2/11091

Author affiliations

Authors

Luong Duy Thanh Thuyloi University, 175 Tay Son, Dong Da, Ha Noi, Vietnam
Rudolf Sprik Van der Waals-Zeeman Institute, University of Amsterdam, The Netherlands

DOI:

https://doi.org/10.15625/0866-7187/40/2/11091

Keywords:

streaming potential, zeta potential, porous media, rocks, electrolytes

Abstract

Streaming potential in rocks is the electrical potential developing when an ionic fluid flows through the pores of rocks. The zeta potential is a key parameter of streaming potential and it depends on many parameters such as the mineral composition of rocks, fluid properties, temperature etc. Therefore, the zeta potential is different for various rocks and liquids. In this work, streaming potential measurements are performed for five rock samples saturated with six different monovalent electrolytes. From streaming potential coefficients, the zeta potential is deduced. The experimental results are then explained by a theoretical model. From the model, the surface site density for different rocks and the binding constant for different cations are found and they are in good agreement with those reported in literature. The result also shows that (1) the surface site density of Bentheim sandstone mostly composed of silica is the largest of five rock samples; (2) the binding constant is almost the same for a given cation but it increases in the order K_Me(Na⁺) < K_Me(K⁺) < K_Me(Cs⁺) for a given rock.

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