Synthesis and Characterization of RbxMn[Fe(CN)]6 and Mn3[Cr(CN)6]2

Phung Kim Phu, Nguyen Minh Thuan, Tran Nam Trung, Nguyen Van Minh

Abstract


We present the synthesis and detailed characterization of RbxMn[Fe(CN)]6 and Mn3[Cr(CN)6]2 compounds. The composition of the materials significantly depends on the preparation conditions. Analysis of Raman spectroscopic results and X-ray powder diffraction data yielded a further assessment of the changes in structural features. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structure that appear to be associated with the synthesis method used.

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DOI: https://doi.org/10.15625/0868-3166/21/1/87 Display counter: Abstract : 139 views. PDF : 40 views.

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