Development of Novel 3d Printable Graphene-based Composite Towards Fabrication of Thin Film Electrode Material

Hanh Le T. M., T. Thuy Do, T. Dung Hoang, T. Tung Doan, X. Minh Vu, T. Lan Pham, T. Lu Le, D. Lam Tran, T. Dung Nguyen
Author affiliations

Authors

  • Hanh Le T. M. Institute for Tropical Technology, Vietnam Academy of Science and Technology, Vietnam
  • T. Thuy Do Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam and Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • T. Dung Hoang Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • T. Tung Doan Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • X. Minh Vu Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • T. Lan Pham Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • T. Lu Le Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam and Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • D. Lam Tran Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam and Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
  • T. Dung Nguyen Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam and Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

DOI:

https://doi.org/10.15625/0868-3166/30/4/15447

Keywords:

3D printable ink, graphene composite, polyvinyl alcohol, ascorbic acid, electrode material

Abstract

Graphene/polymer composite thin film electrodes have many important applications, but the fabrication of these electrodes is often difficult because of poor processability of graphene. This paper presents the primary results on using 3D printing technique for thin film electrode preparation from graphene-based composite ink. The printing ink was synthesized from graphene oxide (GO), polyvinyl alcohol (PVA) as a binder and stabilizer, and ascorbic acid (AA) as a reducing agent. The measured zeta potential value showed that PVA can make GO ink more stable, the absolute value of zeta potential increased from 10.1 mV (without PVA) to 31.4 mV (with 12 wt. % PVA). The thin film electrodes can be easily printed using GO/PVA/AA composite ink, and obtained voltammograms recorded on the surface of these electrodes in 5 mM K3[Fe(CN)6]/K4[Fe(CN)6] solution clearly indicated the GO reduction by AA. The best electrochemical properties of printed electrodes were founded in the case of composite ink with wt/wt ratio GO:PVA:AA = 80:12:8. The cyclic voltammetric results demonstrated the linear dependence of the anodic and cathodic signals of redox couple [Fe(CN)6]4-/K3[Fe(CN)6]3- with the   square root of scan rate, indicating a reversible redox reaction on the electrode surface. The thin films printed from GO/PVA/AA composite ink can be used as electrode material for diverse applications in electrochemistry.

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Published

14-11-2020

How to Cite

[1]
H. Le T. M., T. T. Do, T. D. Hoang, T. T. Doan, X. M. Vu, T. L. Pham, T. L. Le, D. L. Tran and T. D. Nguyen, Development of Novel 3d Printable Graphene-based Composite Towards Fabrication of Thin Film Electrode Material, Comm. Phys. 30 (2020) 383. DOI: https://doi.org/10.15625/0868-3166/30/4/15447.

Issue

Vol. 30 No. 4 (2020)

Section

Papers

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Received 01-09-2020
Accepted 13-11-2020
Published 14-11-2020