Characterization of NH\(_3\) Sensing Properties of P3HT+rGO+CNT Composite Films Made by Spin-coating
Author affiliations
DOI:
https://doi.org/10.15625/0868-3166/28/4/12683Keywords:
P3HT rGO CNT composite, surface morphology, UV-Vis spectra, NH3 gas sensors, sensing response.Abstract
Thin films of poly(3-hexylthiophene) (P3HT) incorporated with reduced graphene oxide (rGO) and multi-walled carbon nanotubes (CNTs) were prepared by spin-coating technique. Atomic force microscope (AFM) surface morphology, UV-Vis spectra and NH3 gas sensing of the films were studied. Results showed that the P3HT embedded with a content of 20 wt.% of rGO and 10 % of CNTs (abbreviated to P3GC) resulted in the formation of nanostructured composites, exhibiting 1.50 nm-roughness surface and a semiconducting material with a bandgap of 1.92eV. These structure and composition of the P3GC film are appropriate for making film sensors whose resistance changes as a function of gas concentration. Monitoring ammonia gas by the sensors showed that the responding time of the sensing reached a value as fast as 30 s, the response at ammonia gas content of 10 ppm attained a value as large as 0.8% and the relative sensitivity was of 0.05 %/ppm.
Downloads
Metrics
References
T. Hibbard, K. Crowley, and A. J. Killard, Analytica Chimica Acta, 779 (2013) 6 – 63.
DOI: https://doi.org/10.1016/j.aca.2013.03.051
M. Gardon and J. M. Guilemany, Journal of Materials Science 24 (2013) 1410 – 1421.
DOI: https://doi.org/10.1007/s10854-012-0974-4
J. Janata and M. Josowicz, Nature Materials 2 (2003) 19 – 24.
DOI: https://doi.org/10.1038/nmat768
H. Bai and G. Shi, Sensors, 7 (2007) 267 – 307.
DOI: https://doi.org/10.3390/s7030267
T. Patois, J.-B. Sanchez, and F. Bergeretal, Talanta 17 (2013) 45 – 54.
DOI: https://doi.org/10.1016/j.talanta.2013.08.047
Y.-S. Lee, B.-S. Joo, N.-J. Choi, J.-O. Lim, J.-S. Huh, and D.-D. Lee, Sensors and Actuators B 93 (2003) 148 – 152.
DOI: https://doi.org/10.1016/S0925-4005(03)00207-7
S. Basu and P. Bhattacharyya, Sensors and Actuators B 173 (2012) 1 – 21.
DOI: https://doi.org/10.1016/j.snb.2012.07.092
P. T. Yin, T. H. Kim, J. W. Choi, and K. B. Lee, Physical Chemistry Chemical Physics 15 (2013) 12785 – 12799.
DOI: https://doi.org/10.1039/c3cp51901e
B. H. Chu, J. Nicolosi, C. F. Lo, W. Strupinski, S. J. Pearton, and F. Ren, Electrochemical and Solid State Letters 14 (2011) K43 – K46.
DOI: https://doi.org/10.1149/1.3589250
M. Zhang and Z. Wang, Applied Physics Letters 102 (2013) 213104 – 213106.
DOI: https://doi.org/10.1063/1.4803444
Lam Minh Long, Nguyen Nang Dinh, Hoang Thi Thu, Huynh Tri Phong, and Tran Quang Trung, VNU Journal of Science.: Mathematics. –Physics, 33 (2017) 52 – 60.
DOI: https://doi.org/10.25073/2588-1124/vnumap.4216
Lam Minh Long, Nguyen Nang Dinh, Tran Quang Trung, Journal of Nanomaterials 2016 (2016) Article ID 5849018, 6 pages.
Tran Thị Thao, Tran Quang Trung, Vo-Van Truong, Nguyen Nang Dinh, Journal of Nanomaterials, 2015 (2015) Article ID 463565, 7 pages.
N. Abu-Zahra and M. Algazzar, Journal of Solar Energy Engineering, 136/2 (2013) 021023-1 ÷ 021023-7.
DOI: https://doi.org/10.1115/1.4026100
L. Stobinski, B. Lesiaka, A. Malolepszyc, M. Mazurkiewiczc and B. Mierzwaa, Journal of Electron Spectroscopy and Related Phenomena, 195 (2014) 145 – 154.
DOI: https://doi.org/10.1016/j.elspec.2014.07.003
B. D. Cullity, Elements of X-Ray diffraction, 2nd ed., p. 102, Addison-Wesley Publishing Company, Inc., Reading, MA, 1978.
B. M. Omer, Journal of Nano and Electronic Physics, 5 (2013) 03010-1 ÷ 03010-4.
Y. Wang, L. Zhang, N. Hu, Ying Wang, Y. Zhang, Z. Zhou, Y. Liu, S. Shen, and C. Peng, Nanoscale Research Letters, 9 (2014) Article 251 (12p).
DOI: https://doi.org/10.1186/1556-276X-9-251
O. K. Varghese, P. D. Kichambre, D. Gong, K. G. Ong, E. C. Dickey, and C. A. Grimes, Sensors and Actuators B, 81 (2001) 32 – 41.
DOI: https://doi.org/10.1016/S0925-4005(01)00923-6
L. Aba, Y. Yusuf, Mitrayana, and K. Triyana, Journal of Modern Physics, 3 (2012) 529 – 533.
DOI: https://doi.org/10.4236/jmp.2012.37072
Downloads
Published
How to Cite
Issue
Section
License
Authors who publish with CIP agree with the following terms:- The manuscript is not under consideration for publication elsewhere. When a manuscript is accepted for publication, the author agrees to automatic transfer of the copyright to the editorial office.
- The manuscript should not be published elsewhere in any language without the consent of the copyright holders. Authors have the right to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal’s published version of their work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are encouraged to post their work online (e.g., in institutional repositories or on their websites) prior to or during the submission process, as it can lead to productive exchanges or/and greater number of citation to the to-be-published work (See The Effect of Open Access).
Accepted 19-10-2018
Published 27-12-2018
